2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino}-3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior
文献类型：期刊论文
| 作者 | Liu, Qingyun1,2,3; Zhang, Wenjuan2,3; Jia, Dedong2,3; Hao, Xiang2,3; Redshaw, Carl4; Sun, Wen-Hua2,3
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| 刊名 | APPLIED CATALYSIS A-GENERAL
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| 出版日期 | 2014-04-05 |
| 卷号 | 475页码:195-202 |
| ISSN号 | 0926-860X |
| 关键词 | Alpha-diiminonickel Complex Ethylene Polymerization Highly Branched Polyethylene Bulky Unsymmetrical 2 3-diiminobutane |
| DOI | 10.1016/j.apcata.2014.01.034 |
| 英文摘要 | The series of 2-{2,6-bis[di(4-fluorophenyl)methyl]-4-chlorophenylimino}-3-aryliminobutane derivatives (L1-L5) and their nickel(II) dibromide complexes (Ni1-Ni5) were synthesized, and all organic compounds were fully characterized by the Fourier transform infrared (FT-IR) and nuclear magnetic resonance (NMR) spectroscopy and by elemental analysis, while the nickel complexes were characterized by FT-IR spectroscopy, elemental analysis, as well as by single-crystal X-ray diffraction for two representative examples, namely Ni1 and Ni4. A distorted tetrahedral geometry was observed for these four-coordinate nickel complexes. Upon the activation with either Methylaluminoxane or modified methylaluminoxane as co-catalyst, all nickel complex precatalysts showed very high activity toward ethylene polymerization with activities of up to 10(7) g(PE).mol(-1)(Ni).h(-1), and afforded highly branched polyethylene with a bimodal distribution. (C) 2014 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000335610400025 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52087]  |
| 专题 | 中国科学院化学研究所 化学研究所_工程塑料实验室 |
| 通讯作者 | Redshaw, Carl |
| 作者单位 | 1.Yangtze Univ, Coll Chem & Environm Engn, Jinzhou 434023, Hubei, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 4.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| 推荐引用方式 GB/T 7714 | Liu, Qingyun,Zhang, Wenjuan,Jia, Dedong,et al. 2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino}-3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior[J]. APPLIED CATALYSIS A-GENERAL,2014,475:195-202. |
| APA | Liu, Qingyun,Zhang, Wenjuan,Jia, Dedong,Hao, Xiang,Redshaw, Carl,&Sun, Wen-Hua.(2014).2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino}-3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior.APPLIED CATALYSIS A-GENERAL,475,195-202. |
| MLA | Liu, Qingyun,et al."2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino}-3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior".APPLIED CATALYSIS A-GENERAL 475(2014):195-202. |
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来源：化学研究所
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