Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach
文献类型:期刊论文
作者 | Gao, Yunlong1,2; Liu, Jun3; Liu, Yuhai2; Shi, Jia-jia2,5; Weng, Shifu2; Yang, Limin4; Wen, Xiaodong4; Kang, Tingguo1; Xu, Yizhuang2; Noda, Isao6 |
刊名 | JOURNAL OF MOLECULAR STRUCTURE
![]() |
出版日期 | 2014-07-08 |
卷号 | 1069页码:205-210 |
关键词 | Lanthanide Ions Intermolecular Interaction 2d Asynchronous Spectra Double Asynchronous Orthogonal Sample Design |
ISSN号 | 0022-2860 |
DOI | 10.1016/j.molstruc.2014.03.047 |
英文摘要 | We applied a newly developed technique of DAOSD (double asynchronous orthogonal sample design) approach to probe weak coordination between Nd3+ ions and ethyl acetate. Cross peaks from the 2D asynchronous spectra are successfully used to reveal subtle spectral variation on carbonyl band of ethyl acetate and f-f transition peak of Nd3+, which is relevant to the coordination between Nd3+ and the ester group of ethyl acetate. In addition, we also use C-13 NMR spectra to investigate the Nd3+/ethyl acetate system. The appearance of new weak carbonyl peak around 177.8 ppm provides alternative evidence of the weak coordination between Nd3+ and ester group of ethyl acetate. (C) 2014 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000337989900028 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/52103] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yang, Limin |
作者单位 | 1.Liaoning Univ Tradit Chinese Med, Coll Pharm, Dalian 116600, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Wenshan Univ, Dept Biochem, Wenshan 663000, Peoples R China 4.Peking Univ, Inst Heavy Ion Phys, Sch Phys, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China 5.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China 6.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA |
推荐引用方式 GB/T 7714 | Gao, Yunlong,Liu, Jun,Liu, Yuhai,et al. Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach[J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1069:205-210. |
APA | Gao, Yunlong.,Liu, Jun.,Liu, Yuhai.,Shi, Jia-jia.,Weng, Shifu.,...&Wu, Jinguang.(2014).Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach.JOURNAL OF MOLECULAR STRUCTURE,1069,205-210. |
MLA | Gao, Yunlong,et al."Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach".JOURNAL OF MOLECULAR STRUCTURE 1069(2014):205-210. |
入库方式: OAI收割
来源:化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。