中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach

文献类型:期刊论文

作者Gao, Yunlong1,2; Liu, Jun3; Liu, Yuhai2; Shi, Jia-jia2,5; Weng, Shifu2; Yang, Limin4; Wen, Xiaodong4; Kang, Tingguo1; Xu, Yizhuang2; Noda, Isao6
刊名JOURNAL OF MOLECULAR STRUCTURE
出版日期2014-07-08
卷号1069页码:205-210
关键词Lanthanide Ions Intermolecular Interaction 2d Asynchronous Spectra Double Asynchronous Orthogonal Sample Design
ISSN号0022-2860
DOI10.1016/j.molstruc.2014.03.047
英文摘要We applied a newly developed technique of DAOSD (double asynchronous orthogonal sample design) approach to probe weak coordination between Nd3+ ions and ethyl acetate. Cross peaks from the 2D asynchronous spectra are successfully used to reveal subtle spectral variation on carbonyl band of ethyl acetate and f-f transition peak of Nd3+, which is relevant to the coordination between Nd3+ and the ester group of ethyl acetate. In addition, we also use C-13 NMR spectra to investigate the Nd3+/ethyl acetate system. The appearance of new weak carbonyl peak around 177.8 ppm provides alternative evidence of the weak coordination between Nd3+ and ester group of ethyl acetate. (C) 2014 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000337989900028
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/52103]  
专题中国科学院化学研究所
通讯作者Yang, Limin
作者单位1.Liaoning Univ Tradit Chinese Med, Coll Pharm, Dalian 116600, Peoples R China
2.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
3.Wenshan Univ, Dept Biochem, Wenshan 663000, Peoples R China
4.Peking Univ, Inst Heavy Ion Phys, Sch Phys, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China
5.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China
6.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
推荐引用方式
GB/T 7714
Gao, Yunlong,Liu, Jun,Liu, Yuhai,et al. Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach[J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1069:205-210.
APA Gao, Yunlong.,Liu, Jun.,Liu, Yuhai.,Shi, Jia-jia.,Weng, Shifu.,...&Wu, Jinguang.(2014).Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach.JOURNAL OF MOLECULAR STRUCTURE,1069,205-210.
MLA Gao, Yunlong,et al."Characterization of the coordination between Nd3+ and ester groups by using double asynchronous orthogonal sample design approach".JOURNAL OF MOLECULAR STRUCTURE 1069(2014):205-210.

入库方式: OAI收割

来源:化学研究所

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