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Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State

文献类型：期刊论文

作者Wang, Lixia1; Wang, Dexian1; Wang, Meixiang2
刊名CHINESE JOURNAL OF CHEMISTRY
出版日期2014-10-01
卷号32期号:10页码:1033-1038
关键词Azacalix[2]Pyrimidine[2]Triazine Fragment Coupling Approach One-pot Reaction Self-assembly Hydrogen Bond
ISSN号1001-604X
DOI10.1002/cjoc.201400505
英文摘要A number of azacalix[2]pyrimidine[2]triazines were synthesized in moderate to good yields from both a step-wise fragment coupling approach and a one-pot reaction strategy starting from 4,6-diaminopyrimidines and cyanuric chloride. Nucleophilic aromatic substitution reaction of resulting dichloro-substituted azacalix[2]pyrimidine[2]triazines with NH4Cl led to the formation of NH2-bearing azacalix[2]pyrimidine[2]triazine analogs. Azacalix[2]pyrimidine[2]triazines adopted symmetric 1,3-alternate conformations in solution while twisted 1,3-alternate conformations were observed in the solid state. In the presence of different additives during the growth of single crystals, azacalix[2]pyrimidine[2]triazines containing amino (-NH2) groups gave varied self-assembled structures due to the formation of different intermolecular hydrogen bond motifs.
语种英语
WOS记录号WOS:000343871100017
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/52209]  
专题中国科学院化学研究所
通讯作者Wang, Dexian
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Lixia,Wang, Dexian,Wang, Meixiang. Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State[J]. CHINESE JOURNAL OF CHEMISTRY,2014,32(10):1033-1038.
APA Wang, Lixia,Wang, Dexian,&Wang, Meixiang.(2014).Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State.CHINESE JOURNAL OF CHEMISTRY,32(10),1033-1038.
MLA Wang, Lixia,et al."Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State".CHINESE JOURNAL OF CHEMISTRY 32.10(2014):1033-1038.

入库方式： OAI收割

来源：化学研究所

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