中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A bipolar small molecule based on indacenodithiophene and diketopyrrolopyrrole for solution processed organic solar cells

文献类型:期刊论文

作者Bai, Huitao1,2; Cheng, Pei1,2; Wang, Yifan1,2; Ma, Lanchao1,2; Li, Yongfang1; Zhu, Daoben1; Zhan, Xiaowei1,3
刊名JOURNAL OF MATERIALS CHEMISTRY A
出版日期2014
卷号2期号:3页码:778-784
ISSN号2050-7488
DOI10.1039/c3ta13816j
英文摘要A new linear A-D-A type low band gap small molecule (IDT-2DPP) based on 4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b0]dithiophene (IDT) and 2,5-bis(2-ethylhexyl)-3,6-di(thiophen-2-yl) pyrrolo[3,4-c] pyrrole-1,4(2H,5H)-dione (DPP) was designed and synthesized by Pd-catalyzed Stille coupling reaction. IDT-2DPP exhibits good solubility and good thermal stability with a decomposition temperature of 395 degrees C. IDT-2DPP shows strong absorption from 500 to 700 nm with a high molar extinction coefficient of 1.3 x 10(5) M-1 cm(-1) at the absorption peak (640 nm) in chloroform solution. The HOMO and LUMO levels of IDT-2DPP were estimated to be -5.11 and -3.32 eV, respectively. Solution processed bulk-heterojunction solar cells using IDT-2DPP as a donor material blending with PC71BM as an acceptor yielded a power conversion efficiency of 2.82%, and solar cells using IDT-2DPP as an acceptor material blending with P3HT as a donor yielded a power conversion efficiency of 0.83% with a high V-oc of 1.17 V.
语种英语
WOS记录号WOS:000328644700029
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/52269]  
专题中国科学院化学研究所
通讯作者Zhan, Xiaowei
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Peking Univ, Dept Mat Sci & Engn, Coll Engn, Beijing 100871, Peoples R China
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GB/T 7714
Bai, Huitao,Cheng, Pei,Wang, Yifan,et al. A bipolar small molecule based on indacenodithiophene and diketopyrrolopyrrole for solution processed organic solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(3):778-784.
APA Bai, Huitao.,Cheng, Pei.,Wang, Yifan.,Ma, Lanchao.,Li, Yongfang.,...&Zhan, Xiaowei.(2014).A bipolar small molecule based on indacenodithiophene and diketopyrrolopyrrole for solution processed organic solar cells.JOURNAL OF MATERIALS CHEMISTRY A,2(3),778-784.
MLA Bai, Huitao,et al."A bipolar small molecule based on indacenodithiophene and diketopyrrolopyrrole for solution processed organic solar cells".JOURNAL OF MATERIALS CHEMISTRY A 2.3(2014):778-784.

入库方式: OAI收割

来源:化学研究所

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