Encapsulating Pd Nanoparticles in Double-Shelled Graphene@Carbon Hollow Spheres for Excellent Chemical Catalytic Property
文献类型：期刊论文
| 作者 | Zhang, Zheye1; Xiao, Fei1; Xi, Jiangbo1; Sun, Tai1; Xiao, Shuang1; Wang, Hairong2; Wang, Shuai1; Liu, Yunqi3 |
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2014-02-11 |
| 卷号 | 4 |
| ISSN号 | 2045-2322 |
| DOI | 10.1038/srep04053 |
| 英文摘要 | Double-shelled hollow carbon spheres with reduced graphene oxide (RGO) as inner shell and carbon (C) layer as outer shell have been successfully designed and prepared. This tailor-making structure acts as an excellent capsule for encapsulating with ultrafine Pd nanoparticles (Pd NPs), which could effectively prevent Pd NPs from aggregation and leaching. As a result, the as-obtained RGO@Pd@C nanohybid exhibits superior and stable catalytic performance. With the aid of RGO@Pd@C, the reduction reaction of 4-nitrophenol (4-NP) to 4-aminophenol with NaBH4 as reducing agent can be finished within only 30 s, even the content of Pd is as low as 0.28 wt%. As far as we know, RGO@Pd@C is one of the most effective catalyst for 4-NP reducing reaction up to now. |
| 语种 | 英语 |
| WOS记录号 | WOS:000331284800003 |
| 出版者 | NATURE PUBLISHING GROUP |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52301]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Shuai |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China 2.North China Univ Water Resources & Elect Power, Inst Environm & Municipal Engn, Zhengzhou 450011, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zheye,Xiao, Fei,Xi, Jiangbo,et al. Encapsulating Pd Nanoparticles in Double-Shelled Graphene@Carbon Hollow Spheres for Excellent Chemical Catalytic Property[J]. SCIENTIFIC REPORTS,2014,4. |
| APA | Zhang, Zheye.,Xiao, Fei.,Xi, Jiangbo.,Sun, Tai.,Xiao, Shuang.,...&Liu, Yunqi.(2014).Encapsulating Pd Nanoparticles in Double-Shelled Graphene@Carbon Hollow Spheres for Excellent Chemical Catalytic Property.SCIENTIFIC REPORTS,4. |
| MLA | Zhang, Zheye,et al."Encapsulating Pd Nanoparticles in Double-Shelled Graphene@Carbon Hollow Spheres for Excellent Chemical Catalytic Property".SCIENTIFIC REPORTS 4(2014). |
入库方式： OAI收割
来源：化学研究所
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