Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity
文献类型：期刊论文
| 作者 | Chen, Bingfeng1,2; Li, Fengbo1; Huang, Zhijun1; Lu, Tao1,2; Yuan, Yin1,2; Yuan, Guoqing1 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2014 |
| 卷号 | 7期号:1页码:202-209 |
| 关键词 | Biomass Heterogeneous Catalysis Hydrogenation Nanoparticles Renewable Resources |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201300542 |
| 英文摘要 | Levulinic acid is an important platform molecule from biomass-based renewable resources. A sustainable manufacturing process for this chemical and its derivatives is the enabling factor to harness the renewable resource. An integrated catalytic process to directly convert furfural to levulinate ester was developed based on a bifunctional catalyst of Pt nanoparticles supported on a ZrNb binary phosphate solid acid. The hydrogenation of furfural and the following alcoholysis of furfuryl alcohol were performed over this catalyst in a one-pot conversion model. Mesoporous ZrNb binary phosphate was synthesized by a sol-gel method and had a high surface area of 170.1 m(2)g(-1) and a large average pore size of around 8.0 nm. Pt nanoparticles remained in a monodisperse state on the support, and the reaction over Pt/ZrNbPO4 (Pt loading: 2.0 wt%; Zr/Nb, 1:1) gave a very high selectivity to levulinate derivatives (91% in total). The sustainability of this conversion was greatly improved by the process intensification based on the new catalyst, mild reaction conditions, cost abatement in separation and purification, and utilization of green reagents and solvents. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336802400024 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52343]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Fengbo |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Green Printing, Beijing 100080, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,et al. Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity[J]. CHEMSUSCHEM,2014,7(1):202-209. |
| APA | Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,Lu, Tao,Yuan, Yin,&Yuan, Guoqing.(2014).Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity.CHEMSUSCHEM,7(1),202-209. |
| MLA | Chen, Bingfeng,et al."Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity".CHEMSUSCHEM 7.1(2014):202-209. |
入库方式： OAI收割
来源：化学研究所
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