Vanadyl Di(5-t-butyl-2-(aryliminomethyl) quinolin-8-olate): Synthesis, Characterization, and Ethylene (Co-)Polymerization
文献类型：期刊论文
| 作者 | Yan, Qing1,2; Sun, Zelin1,2; Zhang, Wenjuan1,2; Nomura, Kotohiro3; Sun, Wen-Hua1,2
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| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2014-09-01 |
| 卷号 | 215期号:18页码:1744-1752 |
| 关键词 | 2-(Aryliminomethyl)Quinolin-8-ol Ethylene (Co-) Polymerization Ultrahigh Molecular Weight Polyethylene Vanadyl Complexes |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.201400199 |
| 英文摘要 | A series of vanadyl di(5-t-butyl-2-(aryliminomethyl) quinolin-8-olate) complexes is prepared by the reaction of 5-t-butyl-2-(aryliminomethyl) quinolin-8-ol derivatives with a slight excess of VO(OPr)(3) in toluene. All the vanadyl complexes are fully characterized by elemental analysis and FTIR spectroscopy; moreover, the molecular structures of representative complexes C2 and C3 are further confirmed by single-crystal X-ray diffraction. On activation with diethylaluminum chloride (Et2AlCl) in either the presence or absence of ethyl trichloroacetate (ETA), all the vanadyl complexes exhibit high activities toward ethylene polymerization (up to 1.81 x 10(7) g mol(-1) V h(-1)), producing polyethylenes with ultrahigh molecular weights (up to 1.51 x 10(6) g mol(-1)) and narrow polydispersities. The copolymerizations of ethylene with either norbornene or 1-hexene are also successfully carried out with high activities. |
| 语种 | 英语 |
| WOS记录号 | WOS:000342622800007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52351]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Tokyo Metropolitan Univ, Grad Sch Sci & Engn, Dept Chem, Hachioji, Tokyo 1920397, Japan |
| 推荐引用方式 GB/T 7714 | Yan, Qing,Sun, Zelin,Zhang, Wenjuan,et al. Vanadyl Di(5-t-butyl-2-(aryliminomethyl) quinolin-8-olate): Synthesis, Characterization, and Ethylene (Co-)Polymerization[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2014,215(18):1744-1752. |
| APA | Yan, Qing,Sun, Zelin,Zhang, Wenjuan,Nomura, Kotohiro,&Sun, Wen-Hua.(2014).Vanadyl Di(5-t-butyl-2-(aryliminomethyl) quinolin-8-olate): Synthesis, Characterization, and Ethylene (Co-)Polymerization.MACROMOLECULAR CHEMISTRY AND PHYSICS,215(18),1744-1752. |
| MLA | Yan, Qing,et al."Vanadyl Di(5-t-butyl-2-(aryliminomethyl) quinolin-8-olate): Synthesis, Characterization, and Ethylene (Co-)Polymerization".MACROMOLECULAR CHEMISTRY AND PHYSICS 215.18(2014):1744-1752. |
入库方式： OAI收割
来源：化学研究所
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