中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Two-dimensional Cr2O3 and interconnected graphene-Cr2O3 nanosheets: synthesis and their application in lithium storage

文献类型:期刊论文

作者Zhao, Guixia1; Wen, Tao1; Zhang, Juan2; Li, Jiaxing1; Dong, Huanli2; Wang, Xiangke1; Guo, Yuguo2; Hu, Wenping2
刊名JOURNAL OF MATERIALS CHEMISTRY A
出版日期2014
卷号2期号:4页码:944-948
ISSN号2050-7488
DOI10.1039/c3ta13535g
英文摘要In this manuscript, we have proposed a new facile method for the synthesis of pure Cr2O3 nanosheets without foreign templates for the first time. We used Na2CrO4 and graphene oxide as the oxidant and reductant templates, respectively, in a hydrothermal reaction in order to synthesize porous Cr(OH)(3) nanosheet precursors. By controlling the proportion of graphene oxide and Cr(VI), the carbon framework could be partially retained, resulting in graphene-divided porous Cr(OH)(3) nanosheets. After calcination at 700 degrees C, these graphene oxide-derived Cr(OH)(3) nanosheets were transformed into pure Cr2O3 nanosheets or interconnected graphene-Cr2O3 nanomaterials. The graphene-Cr2O3 nanosheets exhibited an excellent rate capability and cycling performance as an anode material in lithium ion batteries (LIB), as well as a high reversible capacity of 850 mA h g(-1) at a current density of 200 mA g(-1), which is the highest capacity reported for Cr2O3 anode materials.
语种英语
WOS记录号WOS:000328886800010
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/52383]  
专题中国科学院化学研究所
通讯作者Wang, Xiangke
作者单位1.Acad Sinica, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cells, Hefei 230031, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Guixia,Wen, Tao,Zhang, Juan,et al. Two-dimensional Cr2O3 and interconnected graphene-Cr2O3 nanosheets: synthesis and their application in lithium storage[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(4):944-948.
APA Zhao, Guixia.,Wen, Tao.,Zhang, Juan.,Li, Jiaxing.,Dong, Huanli.,...&Hu, Wenping.(2014).Two-dimensional Cr2O3 and interconnected graphene-Cr2O3 nanosheets: synthesis and their application in lithium storage.JOURNAL OF MATERIALS CHEMISTRY A,2(4),944-948.
MLA Zhao, Guixia,et al."Two-dimensional Cr2O3 and interconnected graphene-Cr2O3 nanosheets: synthesis and their application in lithium storage".JOURNAL OF MATERIALS CHEMISTRY A 2.4(2014):944-948.

入库方式: OAI收割

来源:化学研究所

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