N-Annulated Perylene as a Coplanar pi-Linker Alternative to Benzene as a Low Energy-Gap, Metal-Free Dye in Sensitized Solar Cells
文献类型：期刊论文
| 作者 | Yao, Zhaoyang1,2; Yan, Cancan1,2; Zhang, Min1; Li, Renzhi1; Cai, Yanchun1; Wang, Peng1 |
| 刊名 | ADVANCED ENERGY MATERIALS
 |
| 出版日期 | 2014-08-26 |
| 卷号 | 4期号:12 |
| ISSN号 | 1614-6832 |
| DOI | 10.1002/aenm.201400244 |
| 英文摘要 | Perylenes are well-known pigments with excellent chemical, thermal, and photochemical stabilities and have been used in various optical and electronic fields. Although for sensitized mesoscopic solar cells there is rapid progress of metal-free thiophene dyes, which now reach over 11.5% power conversion efficiency (PCE) at air mass 1.5 global (AM1.5G) conditions, the so far reported highest PCE of a perylene dye is only 6.8%. Here, a new metal-free organic donor-acceptor (D-A) dye (C261) featuring a bisarylamino functionalized N-annulated perylene electron-releasing segment and a cyanoacrylic acid electron-withdrawing unit is synthesized. Combining a mesoporous titania film grafted by this structurally simple perylene dye with a non-corrosive cobalt redox shuttle, an 8.8% PCE is achieved at an irradiance of the AM1.5G sunlight. By selecting the model dye G221 as a reference, theoretical calculations, steady-state and time-resolved spectroscopies, and electrical measurements are used to compare the energy-levels, light absorptions, and mutichannel charge transfer dynamics that contribute to the photovoltaic behavior. |
| 语种 | 英语 |
| WOS记录号 | WOS:000341234600015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52445]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Peng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Zhaoyang,Yan, Cancan,Zhang, Min,et al. N-Annulated Perylene as a Coplanar pi-Linker Alternative to Benzene as a Low Energy-Gap, Metal-Free Dye in Sensitized Solar Cells[J]. ADVANCED ENERGY MATERIALS,2014,4(12). |
| APA | Yao, Zhaoyang,Yan, Cancan,Zhang, Min,Li, Renzhi,Cai, Yanchun,&Wang, Peng.(2014).N-Annulated Perylene as a Coplanar pi-Linker Alternative to Benzene as a Low Energy-Gap, Metal-Free Dye in Sensitized Solar Cells.ADVANCED ENERGY MATERIALS,4(12). |
| MLA | Yao, Zhaoyang,et al."N-Annulated Perylene as a Coplanar pi-Linker Alternative to Benzene as a Low Energy-Gap, Metal-Free Dye in Sensitized Solar Cells".ADVANCED ENERGY MATERIALS 4.12(2014). |
入库方式： OAI收割
来源：化学研究所
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