Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s
文献类型：期刊论文
| 作者 | Tian, Hongkun; Chen, Yagang; Li, Weili; Yan, Donghang; Geng, Yanhou; Wang, Fosong |
| 刊名 | ORGANIC ELECTRONICS
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 15期号:6页码:1088-1095 |
| 关键词 | Naphthalene Conjugated Oligomer Organic Semiconductors Organic Thin-film Transistors Field-effect Mobility |
| ISSN号 | 1566-1199 |
| DOI | 10.1016/j.orgel.2014.02.018 |
| 英文摘要 | Oligo(2,6-naphthalene)s (nNs) with the number of repeating unit (n) of 3-5 and dioctyl substituted trimer (DO-3N) and tetramer (DO-4N) were synthesized and characterized. Except of DO-4N that decomposed at 331 degrees C, all other oligomers display good thermal stability with 5% weight loss temperatures beyond 350 degrees C. For 4N and DO-4N, only one phase transition corresponding to melting can be found. However, DO-3N and 5N exhibit multiple phase transitions. The film absorption maximum of the oligomers at the long wavelength exhibits a red-shift with increasing the number of repeating unit. Meanwhile, the highest occupied molecular orbital (HOMO) levels increase from -5.96 eV of 3N to 5.91 eV of 4N and then 5.85 eV of 5N. The introduction of octyl group has negligible effect on the photophysical properties. Highly ordered films of 4N, 5N, DO-3N and DO-4N in which the molecules orient with their long axis standing on the substrates can be prepared by vacuum deposition. Organic thin-film transistors (OTFTs) with top-contact and bottom-gate geometry have been fabricated based on these films. The introduction of octyl groups results in the films with higher order and therefore higher field-effect mobilities (mu) of OTFT devices. Among these oligomers, DO-3N exhibits the highest mobility of 0.50 cm(2)/V s when the film deposited on the octyltrichlorosilane (OTS) modified substrate. (C) 2014 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000334740100003 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52455]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tian, Hongkun |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Hongkun,Chen, Yagang,Li, Weili,et al. Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s[J]. ORGANIC ELECTRONICS,2014,15(6):1088-1095. |
| APA | Tian, Hongkun,Chen, Yagang,Li, Weili,Yan, Donghang,Geng, Yanhou,&Wang, Fosong.(2014).Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s.ORGANIC ELECTRONICS,15(6),1088-1095. |
| MLA | Tian, Hongkun,et al."Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s".ORGANIC ELECTRONICS 15.6(2014):1088-1095. |
入库方式： OAI收割
来源：化学研究所
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