Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation
文献类型：期刊论文
| 作者 | Liu, Hui1,2; Wei, Jianpeng1; Qiao, Zongjun1; Fu, Yana1; Jiang, Xuefeng1,3,4 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 20期号:27页码:8308-8313 |
| 关键词 | Catalysis C-c Bond Formation Cross-coupling Csp(3)-x Bond Palladium |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201403093 |
| 英文摘要 | A Pd-catalyzed efficient reductive cross-coupling reaction without metallic reductant to construct a Csp(2)-Csp(3) bond has been reported. A Pd-IV complex was proposed to be a key intermediate, which subsequently went through double oxidative addition and double reductive elimination to produce the cross-coupling products by involving Pd-0/II/IV in one transformation. The oxidative addition from Pd-II to Pd-IV was partially demonstrated to be a radical process by self-oxidation of substrate without additional oxidants. Furthermore, the solvent was proved to be the reductant for this transformation through XPS analysis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000338019300012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52489]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Xuefeng |
| 作者单位 | 1.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China 2.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China 3.Peking Univ, BNLMS, Beijing, Peoples R China 4.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hui,Wei, Jianpeng,Qiao, Zongjun,et al. Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(27):8308-8313. |
| APA | Liu, Hui,Wei, Jianpeng,Qiao, Zongjun,Fu, Yana,&Jiang, Xuefeng.(2014).Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation.CHEMISTRY-A EUROPEAN JOURNAL,20(27),8308-8313. |
| MLA | Liu, Hui,et al."Palladium-Catalyzed Intramolecular Reductive Cross-Coupling of Csp(2)-Csp(3) Bond Formation".CHEMISTRY-A EUROPEAN JOURNAL 20.27(2014):8308-8313. |
入库方式： OAI收割
来源：化学研究所
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