Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion
文献类型：期刊论文
| 作者 | Wang, Xi1,2; Zhou, Yujing1,2; Ji, Guojing1,2,3; Wu, Guojiao1,2; Li, Ming3; Zhang, Yan1,2; Wang, Jianbo1,2 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-05-01 |
| 卷号 | 2014期号:15页码:3093-3096 |
| 关键词 | Diazo Compounds Carbenes Fluorine Migratory Insertion |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201402105 |
| 英文摘要 | A strategy to introduce the SCF3 group through the Cu-I-promoted reaction of diazo compounds with the nucleophilic AgSCF3 trifluoromethylthiolation reagent was developed. Various diazo compounds were smoothly converted under mild conditions to form the C(sp(3))-SCF3 bond. Mechanistically, migratory insertion of SCF3-bearing Cu carbene intermediates is involved in this transformation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336377000007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52511]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xi,Zhou, Yujing,Ji, Guojing,et al. Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014,2014(15):3093-3096. |
| APA | Wang, Xi.,Zhou, Yujing.,Ji, Guojing.,Wu, Guojiao.,Li, Ming.,...&Wang, Jianbo.(2014).Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014(15),3093-3096. |
| MLA | Wang, Xi,et al."Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2014.15(2014):3093-3096. |
入库方式： OAI收割
来源：化学研究所
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