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Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring

文献类型：期刊论文

作者Zhao, Jing1; Zhang, Shaoguang2; Zhang, Wen-Xiong2; Xi, Zhenfeng2,3
刊名ORGANOMETALLICS
出版日期2014-01-13
卷号33期号:1页码:8-11
ISSN号0276-7333
DOI10.1021/om401065c
英文摘要The reaction of titanacyclobutene-silacyclobutene fused-ring complexes with nitriles was investigated. Formal insertion of the C-N triple bond of nitriles into the silacyclobutene ring was observed, affording their corresponding titanacyclobutene and six-membered azasilacycle fused-ring complexes. This reaction pattern with nitriles is totally different from that of their analogous zirconacyclobutene-silacyclobutene fused-ring complexes. The size effect of the central metals (Ti vs Zr) is considered as the major reason for the different reaction patterns.
语种英语
WOS记录号WOS:000329879900002
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/52527]  
专题中国科学院化学研究所
通讯作者Zhang, Wen-Xiong
作者单位1.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
3.Chinese Acad Sci, SIOC, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714		 Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring[J]. ORGANOMETALLICS,2014,33(1):8-11.
APA Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring.ORGANOMETALLICS,33(1),8-11.
MLA Zhao, Jing,et al."Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring".ORGANOMETALLICS 33.1(2014):8-11.

入库方式： OAI收割

来源：化学研究所

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