Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring
文献类型:期刊论文
作者 | Zhao, Jing1; Zhang, Shaoguang2; Zhang, Wen-Xiong2; Xi, Zhenfeng2,3 |
刊名 | ORGANOMETALLICS
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出版日期 | 2014-01-13 |
卷号 | 33期号:1页码:8-11 |
ISSN号 | 0276-7333 |
DOI | 10.1021/om401065c |
英文摘要 | The reaction of titanacyclobutene-silacyclobutene fused-ring complexes with nitriles was investigated. Formal insertion of the C-N triple bond of nitriles into the silacyclobutene ring was observed, affording their corresponding titanacyclobutene and six-membered azasilacycle fused-ring complexes. This reaction pattern with nitriles is totally different from that of their analogous zirconacyclobutene-silacyclobutene fused-ring complexes. The size effect of the central metals (Ti vs Zr) is considered as the major reason for the different reaction patterns. |
语种 | 英语 |
WOS记录号 | WOS:000329879900002 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/52527] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, Wen-Xiong |
作者单位 | 1.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Chinese Acad Sci, SIOC, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring[J]. ORGANOMETALLICS,2014,33(1):8-11. |
APA | Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring.ORGANOMETALLICS,33(1),8-11. |
MLA | Zhao, Jing,et al."Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring".ORGANOMETALLICS 33.1(2014):8-11. |
入库方式: OAI收割
来源:化学研究所
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