Electrochemical behaviors of protonated diamines at the micro-water/1,2-dichloroethane interface
文献类型：期刊论文
| 作者 | Li, Bo1; Qiao, Yonghui1; Gu, Jing1; Zhu, Xinyu1; Yin, Xiaohong1; Li, Qing1; Zhu, Zhiwei1; Li, Meixian1; Jing, Ping2; Shao, Yuanhua1 |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2014-07-24 |
| 卷号 | 726页码:21-26 |
| 关键词 | Liquid/liquid Interface Diamines Ion Transfer And Facilitated Ion Transfer |
| ISSN号 | 1572-6657 |
| DOI | 10.1016/j.jelechem.2014.05.007 |
| 英文摘要 | The simple ion transfer (IT) and facilitated ion transfer (FIT) of a series of protonated diamines ([H3N(CH2)(n)NH3](2+) (DA(2+)) or [H2N(CH2)(n)NH3](+) (DA(+)), n = 2,3, 4, 6, 8) at the micro-water/1,2-dichloroethane (mu-W/DCE) interface supported at the tip of a micropipette are reported. The effect of pH on both transfer processes has been studied in detail. For the IT process at low pH, DA(2+) is dominated whereas at high pH it is mostly due to the DA(+) transfer. The experimental results also demonstrate that dibenzo-18-crown-6 (DB18C6, L) can facilitate the transfer of protonated diamines at such interface. The complexation between ion and ligand is 1:1 at all experimental pH when C-DA(z+) >> CL (where z can be 0, 1 or 2 depending on the pH of solutions). For C-DA(z+) << C-L, the ion to ligand stoichiometry is 1:1 when pH is high, and is 1:2 when pH is low. The association constants for both cases are also calculated. Among these five diamines, the association constant for protonated 1,3-propanediamine has the biggest values. (C) 2014 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000340018900004 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52651]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jing, Ping |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Shandong Entry Exit Inspect & Quarantine Bur, Ctr Tech, Qingdao 266002, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Bo,Qiao, Yonghui,Gu, Jing,et al. Electrochemical behaviors of protonated diamines at the micro-water/1,2-dichloroethane interface[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2014,726:21-26. |
| APA | Li, Bo.,Qiao, Yonghui.,Gu, Jing.,Zhu, Xinyu.,Yin, Xiaohong.,...&Shao, Yuanhua.(2014).Electrochemical behaviors of protonated diamines at the micro-water/1,2-dichloroethane interface.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,726,21-26. |
| MLA | Li, Bo,et al."Electrochemical behaviors of protonated diamines at the micro-water/1,2-dichloroethane interface".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 726(2014):21-26. |
入库方式： OAI收割
来源：化学研究所
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