中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Short-conjugated zwitterionic cyanopyridinium chromophores: Synthesis, crystal structure, and linear/nonlinear optical properties

文献类型:期刊论文

作者Hao, Wen Hui1,2; Yan, Pengfei1; Li, Guangming1; Wang, Zhi Yuan2,3
刊名DYES AND PIGMENTS
出版日期2014-12-01
卷号111页码:145-155
关键词Zwitterionic Chromophores Hyperpolarizability Solvatochromism Nonlinear Optical Electro-optic Fluorescence
ISSN号0143-7208
DOI10.1016/j.dyepig.2014.06.005
英文摘要A new class of short-conjugated zwitterionic cyanopyridinium chromophores with the absorption maxima less than 550 nm were designed and synthesized. These chromophores display a good solubility in organic solvents and exist in a charge-separated ground state, as confirmed by IR, X-ray crystallography, negative solvatochromism and fluorescence studies. They can be doped up to 10% by weight into poly(ether sulfone) and attached onto a methacrylate polymer by grafting. Without optimization of the poling conditions, a high electro-optic coefficient can be readily achieved using the chromophore-grafted nonlinear optical polymers. (C) 2014 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000340976400019
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/52661]  
专题中国科学院化学研究所
通讯作者Wang, Zhi Yuan
作者单位1.Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem MOE, Harbin 150080, Peoples R China
2.Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada
3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
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GB/T 7714
Hao, Wen Hui,Yan, Pengfei,Li, Guangming,et al. Short-conjugated zwitterionic cyanopyridinium chromophores: Synthesis, crystal structure, and linear/nonlinear optical properties[J]. DYES AND PIGMENTS,2014,111:145-155.
APA Hao, Wen Hui,Yan, Pengfei,Li, Guangming,&Wang, Zhi Yuan.(2014).Short-conjugated zwitterionic cyanopyridinium chromophores: Synthesis, crystal structure, and linear/nonlinear optical properties.DYES AND PIGMENTS,111,145-155.
MLA Hao, Wen Hui,et al."Short-conjugated zwitterionic cyanopyridinium chromophores: Synthesis, crystal structure, and linear/nonlinear optical properties".DYES AND PIGMENTS 111(2014):145-155.

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来源:化学研究所

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