Combination of ATRA and ATRC for the Synthesis of Periodic Vinyl Copolymers
文献类型：期刊论文
| 作者 | Wang, Chun-Hao; Song, Zi-Yuan; Deng, Xin-Xing; Zhang, Li-Jing; Du, Fu-Sheng; Li, Zi-Chen |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 35期号:4页码:474-478 |
| 关键词 | Atom Transfer Radical Addition (Atra) Atom Transfer Radical Coupling (Atrc) Copolymer Periodic Sequence |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.201300721 |
| 英文摘要 | A new approach to periodic vinyl copolymers via combination of atom transfer radical addition (ATRA) and atom transfer radical coupling (ATRC) is reported. The two examples are methyl methacrylate (MMA) and styrene (St) periodic copolymer (P(SMMS)) and acrylonitrile (AN) and St periodic copolymer (P(SAAS)). First, two monomer sequence units (MSU) with built-in sequence, SMMS and SAAS, are synthesized through the controlled ATRA of two ATRP initiators with St. Then, the ATRC of SMMS and SAAS are conducted at high radical conditions to generate two types of high-molecular-weight copolymers, P(SMMS) and P(SAAS). Though side reactions can not be totally avoided, characterizations of the polymer structure with a variety of means confirm that the main chain structures of P(SMMS) and (PSAAS) are predominantly with the periodic sequences from the MSUs. Attempts to suppress the side reactions are successful via the MNP-mediated ATRC of SMMS and SAAS. |
| 语种 | 英语 |
| WOS记录号 | WOS:000331998700015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52671]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zi-Chen |
| 作者单位 | Peking Univ, BNLMS, Key Lab Polymer Chem & Phys, Minist Educ,Dept Polymer Sci & Engn,Coll Chem & M, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chun-Hao,Song, Zi-Yuan,Deng, Xin-Xing,et al. Combination of ATRA and ATRC for the Synthesis of Periodic Vinyl Copolymers[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2014,35(4):474-478. |
| APA | Wang, Chun-Hao,Song, Zi-Yuan,Deng, Xin-Xing,Zhang, Li-Jing,Du, Fu-Sheng,&Li, Zi-Chen.(2014).Combination of ATRA and ATRC for the Synthesis of Periodic Vinyl Copolymers.MACROMOLECULAR RAPID COMMUNICATIONS,35(4),474-478. |
| MLA | Wang, Chun-Hao,et al."Combination of ATRA and ATRC for the Synthesis of Periodic Vinyl Copolymers".MACROMOLECULAR RAPID COMMUNICATIONS 35.4(2014):474-478. |
入库方式： OAI收割
来源：化学研究所
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