Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations
文献类型：期刊论文
| 作者 | Fang, Huayi1; Ling, Zhen1; Lang, Ke1; Brothers, Penelope J.2; de Bruin, Bas3; Fu, Xuefeng1 |
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2014-03-01 |
| 卷号 | 5期号:3页码:916-921 |
| ISSN号 | 2041-6520 |
| DOI | 10.1039/c3sc52326h |
| 英文摘要 | The [(TPFC)Ge(TEMPO)] (1, TPFC = tris(pentafluorophenyl)corrole, TEMPO = (2,2,6,6-tetramethylpiperidin-1-yl)oxyl) complex was characterized by X-ray diffraction and spectroscopic studies. EPR studies indicate that the weak Ge-O bond in 1 is photo-cleaved to form a tetra-coordinated germanium(m) radical, [(TPFC)Ge(III)](center dot). DFT calculations show that the spin density on the germanium center in [(TPFC)Ge(III)](center dot). has a significant s character. Under visible-light irradiation, 1 reacts rapidly with ammonia, primary/secondary aliphatic amines and aniline to produce (TPFC)Ge-(NRR2)-R-1 ((RR2)-R-1 = HH, (HPr)-Pr-n, (HPr)-Pr-i, (HBu)-Bu-t, HPh, Et-2, Pr-i(2)) complexes in high yields (65-95%). |
| 语种 | 英语 |
| WOS记录号 | WOS:000332189900007 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52677]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | de Bruin, Bas |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Univ Auckland, Sch Chem Sci, Auckland 1042, New Zealand 3.Univ Amsterdam, Vant Hoff Inst Mol Sci HIMS, NL-1098 XH Amsterdam, Netherlands |
| 推荐引用方式 GB/T 7714 | Fang, Huayi,Ling, Zhen,Lang, Ke,et al. Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations[J]. CHEMICAL SCIENCE,2014,5(3):916-921. |
| APA | Fang, Huayi,Ling, Zhen,Lang, Ke,Brothers, Penelope J.,de Bruin, Bas,&Fu, Xuefeng.(2014).Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations.CHEMICAL SCIENCE,5(3),916-921. |
| MLA | Fang, Huayi,et al."Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations".CHEMICAL SCIENCE 5.3(2014):916-921. |
入库方式： OAI收割
来源：化学研究所
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