Cyclopolymerization of alpha,omega-Heterodifunctional Monomers Containing Styrene and Maleimide Moieties
文献类型：期刊论文
| 作者 | Zou, Lei1; Liu, Jian'an2; Zhang, Ke1; Chen, Yongming1; Xi, Fu1 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 52期号:3页码:330-338 |
| 关键词 | Cyclopolymerization Host-guest Systems Reversible Addition-fragmentation Chain Transfer Polymerization (Raft) |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.27004 |
| 英文摘要 | A series of ,-heterodifunctional monomers with styrene (St) and maleimide moieties bridged by a varied length of oligo-ethylene glycol (OEG) linkers were synthesized. Cyclopolymerizations of these monomers through reversible addition-fragmentation chain transfer-mediated alternating radical copolymerization between intramolecular St and maleimide moieties were investigated. For the monomers with three or more ethylene glycol (EG) units, their cyclopolymerizations can be realized properly in low monomer feeding concentrations, affording well-defined cyclopolymers with crown ether encircled in their main chains. Importantly, the cyclopolymerizations of monomers with six or seven EG units in the presence of KPF6 could be enhanced by the supramolecular effects between the OEG linkers and the potassium metal ion. Thus, the monomer feeding concentration could be largely improved, which may benefit preparation of the cyclopolymers with high degrees of copolymerization. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 330-338 |
| 语种 | 英语 |
| WOS记录号 | WOS:000328481200005 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52731]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Yongming |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Mass Spectrometry Ctr, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou, Lei,Liu, Jian'an,Zhang, Ke,et al. Cyclopolymerization of alpha,omega-Heterodifunctional Monomers Containing Styrene and Maleimide Moieties[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2014,52(3):330-338. |
| APA | Zou, Lei,Liu, Jian'an,Zhang, Ke,Chen, Yongming,&Xi, Fu.(2014).Cyclopolymerization of alpha,omega-Heterodifunctional Monomers Containing Styrene and Maleimide Moieties.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,52(3),330-338. |
| MLA | Zou, Lei,et al."Cyclopolymerization of alpha,omega-Heterodifunctional Monomers Containing Styrene and Maleimide Moieties".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 52.3(2014):330-338. |
入库方式： OAI收割
来源：化学研究所
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