Synergistic Effect of Aluminum Hydroxide and Expandable Graphite on the Flame Retardancy of Polyisocyanurate-Polyurethane Foams
文献类型：期刊论文
| 作者 | Wang, Wanjin1,2; He, Kui2; Dong, Quanxiao2; Zhu, Ning2; Fan, Yong2; Wang, Feng3; Xia, Yibing2; Li, Haifeng2; Wang, Jing2; Yuan, Zhen2 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2014-02-15 |
| 卷号 | 131期号:4 |
| 关键词 | Flame Retardance Polyurethanes Thermal Properties Foams Degradation |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.39936 |
| 英文摘要 | For the first time, expandable graphite (EG) and aluminum hydroxide (ATH) was combined to improve the flame retardancy of polyisocyanurate-polyurethane (PIR-PUR) foam. The limited oxygen index increased from 26.5 for the PIR-PUR matrix to an incredible value of 92.8 when 24 phr (parts per 100 of matrix) EG and 60 phr ATH were incorporated into the matrix. Based on morphology observation and thermogravimetric analysis, it was speculated that two factors contributed to the improvement of flame retardancy primarily. First, ATH could effectively induce villi like particles, which was useful to form a dense char. The compact char layer could effectively impede the transport of bubbles and heat. Second, ATH and EG accelerated the initial degradation and fluffy char was quickly generated on the surface of the composites. Thus, the degradation of the composite was slowed down and the diffusion of volatile combustible fragments to flame zone was delayed. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39936. |
| 语种 | 英语 |
| WOS记录号 | WOS:000331066200036 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52759]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Dong, Quanxiao |
| 作者单位 | 1.China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China 2.Beijing Bldg Construct Res Inst Co Ltd, Beijing Engn Res Ctr Architectural Funct Macromo, Beijing 100039, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Engn Plast, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Wanjin,He, Kui,Dong, Quanxiao,et al. Synergistic Effect of Aluminum Hydroxide and Expandable Graphite on the Flame Retardancy of Polyisocyanurate-Polyurethane Foams[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2014,131(4). |
| APA | Wang, Wanjin.,He, Kui.,Dong, Quanxiao.,Zhu, Ning.,Fan, Yong.,...&Yang, Mingshu.(2014).Synergistic Effect of Aluminum Hydroxide and Expandable Graphite on the Flame Retardancy of Polyisocyanurate-Polyurethane Foams.JOURNAL OF APPLIED POLYMER SCIENCE,131(4). |
| MLA | Wang, Wanjin,et al."Synergistic Effect of Aluminum Hydroxide and Expandable Graphite on the Flame Retardancy of Polyisocyanurate-Polyurethane Foams".JOURNAL OF APPLIED POLYMER SCIENCE 131.4(2014). |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。