2,6-Anthracenyl(anthraquinonyl)-substituted difluoroboron dipyrromethenes: Synthesis, spectroscopy, electrochemistry and quantum chemical calculations
文献类型：期刊论文
| 作者 | Xu, Liang1,2; Li, Yongjun1; Jiang, Runsheng1,2; Qin, Zhihong1,2; Li, Yuliang1 |
| 刊名 | DYES AND PIGMENTS
 |
| 出版日期 | 2014-08-01 |
| 卷号 | 107页码:90-96 |
| 关键词 | Anthracene Anthraquinone Bodipy Donor-acceptor Gaussian Calculation Intramolecular Charge-transfer |
| ISSN号 | 0143-7208 |
| DOI | 10.1016/j.dyepig.2014.03.032 |
| 英文摘要 | A series of anthracenyl(anthraquinonyl)-substituted difluoroboron dipyrromethene dyes were synthesized through a Suzuki cross-coupling reaction. The crystal structure combined with geometric optimization reveals a moderate dihedral angle between the anthracenyl(anthraquinonyl) plane and the connected pyrrolyl plane. Photophysical characterization shows that the introduction of anthracenyl(anthraquinonyl) moiety to the BODIPY core effectively tunes the emission properties of BODIPY while retaining the separate absorption properties of BODIPY and anthracene(anthraquinone). High fluorescent quantum yields of up to 0.70 and a large Stokes shift (ca. 1707 cm(-1)) were noted. Electrochemical characterization suggests that the anthracenyl(anthraquinonyl) linkage and BODIPY unit lead to rich and tunable potentials. TD-DFT calculation proved a moderate intramolecular charge-transfer process between the BODIPY core and anthracenyl(anthraquinonyl) moiety. (C) 2014 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336828900012 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52787]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yongjun |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Liang,Li, Yongjun,Jiang, Runsheng,et al. 2,6-Anthracenyl(anthraquinonyl)-substituted difluoroboron dipyrromethenes: Synthesis, spectroscopy, electrochemistry and quantum chemical calculations[J]. DYES AND PIGMENTS,2014,107:90-96. |
| APA | Xu, Liang,Li, Yongjun,Jiang, Runsheng,Qin, Zhihong,&Li, Yuliang.(2014).2,6-Anthracenyl(anthraquinonyl)-substituted difluoroboron dipyrromethenes: Synthesis, spectroscopy, electrochemistry and quantum chemical calculations.DYES AND PIGMENTS,107,90-96. |
| MLA | Xu, Liang,et al."2,6-Anthracenyl(anthraquinonyl)-substituted difluoroboron dipyrromethenes: Synthesis, spectroscopy, electrochemistry and quantum chemical calculations".DYES AND PIGMENTS 107(2014):90-96. |
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来源：化学研究所
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