Preparation of functionalized graphene/SEBS-g-MAH nanocomposites and improvement of its electrical, mechanical properties
文献类型:期刊论文
作者 | Shi, Hengchong1,3; Shi, Dean2; Li, Cong2; Luan, Shifang1; Yin, Jinghua1; Li, Robert K. Y.3 |
刊名 | MATERIALS LETTERS |
出版日期 | 2014-10-15 |
卷号 | 133页码:200-203 |
ISSN号 | 0167-577X |
关键词 | Graphene Nanocomposites Electrical Properties Mechanical Properties |
DOI | 10.1016/j.matlet.2014.06.161 |
英文摘要 | Graphene was first surface modified with octadecylamine to prevent the aggregation of graphene itself and also improve the compatibility between the graphene and polymer matrix. Then it was solution mixed with SEBS grafted with maleic anhydride (SEBS-g-MAH) to prepare graphene/SEBS-g-MAH nanocomposites. FTIR results show that esterification reaction took place by a "grafting to" method between maleic anhydride group of SEBS-g-MAH and the residual hydroxyl of graphene. Rheological data indicated that storage modulus increased sharply with 0.5 wt% addition content of graphene, due to forming the network of graphene in SEBS-g-MAH. The tensile strength was enhanced by 69%, ranging from 1.94 to 3.28 MPa. The alternating current conductivity at 1 Hz of nanocomposites increased from 2.5 x 10(-16) to 1.2 x 10(-11) S/cm, compared with that of SEBS-g-MAH. The above results were attributed to the good dispersion of graphene in SEBS-g-MAH matrix and interfacial chemical interaction between graphene and SEBS-g-MAH. (C) 2014 Elsevier B.V. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000341555800053 |
源URL | [http://ir.iccas.ac.cn/handle/121111/52825] |
专题 | 中国科学院化学研究所 |
通讯作者 | Shi, Dean |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Hubei Univ, Fac Mat Sci & Engn, Key Lab Green Preparat & Applicat Funct Mat, Minist Educ, Wuhan 430062, Peoples R China 3.City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China |
推荐引用方式 GB/T 7714 | Shi, Hengchong,Shi, Dean,Li, Cong,et al. Preparation of functionalized graphene/SEBS-g-MAH nanocomposites and improvement of its electrical, mechanical properties[J]. MATERIALS LETTERS,2014,133:200-203. |
APA | Shi, Hengchong,Shi, Dean,Li, Cong,Luan, Shifang,Yin, Jinghua,&Li, Robert K. Y..(2014).Preparation of functionalized graphene/SEBS-g-MAH nanocomposites and improvement of its electrical, mechanical properties.MATERIALS LETTERS,133,200-203. |
MLA | Shi, Hengchong,et al."Preparation of functionalized graphene/SEBS-g-MAH nanocomposites and improvement of its electrical, mechanical properties".MATERIALS LETTERS 133(2014):200-203. |
入库方式: OAI收割
来源:化学研究所
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