Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak
文献类型：期刊论文
| 作者 | Li, Xiaopei1,2,3; Fan, Xiaokun1,4; Huang, Kun1; Liu, Huizhou1; Zhao, Ying5; Wei, Yongju4; Liu, Cuige4; Xu, Yizhuang2; Noda, Isao6; Wu, Jinguang2 |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2014-07-08 |
| 卷号 | 1069页码:127-132 |
| ISSN号 | 0022-2860 |
| 关键词 | Two-dimensional Asynchronous Spectroscopy Intermolecular Interaction Asynchronous |
| DOI | 10.1016/j.molstruc.2014.01.046 |
| 英文摘要 | We explore whether it is possible to use 2D correlation spectrum to characterize intermolecular interactions between two solutes dissolved in the same solution when one substance does not possesses any characteristic peak. We demonstrate that the interaction can be manifested by characteristic cross peaks in 2D asynchronous correlated spectrum. The above cross peaks reflect the subtle spectral variations on the characteristic peak of another solute under intermolecular interaction. On the other hand, 2D synchronous spectrum is not suitable to characterize intermolecular interaction since the cross peaks contain irremovable interfering parts. The terbium-chloride/benzamide/methanol system is used to demonstrate that this approach is applicable in the real chemical system. (C) 2014 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000337989900015 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52831]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Kun |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 6.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA |
| 推荐引用方式 GB/T 7714 | Li, Xiaopei,Fan, Xiaokun,Huang, Kun,et al. Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak[J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1069:127-132. |
| APA | Li, Xiaopei.,Fan, Xiaokun.,Huang, Kun.,Liu, Huizhou.,Zhao, Ying.,...&Wu, Jinguang.(2014).Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak.JOURNAL OF MOLECULAR STRUCTURE,1069,127-132. |
| MLA | Li, Xiaopei,et al."Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak".JOURNAL OF MOLECULAR STRUCTURE 1069(2014):127-132. |
入库方式： OAI收割
来源：化学研究所
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