中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes

文献类型:期刊论文

作者Zhao, Jing1; Zhang, Shaoguang2; Zhang, Wen-Xiong2; Xi, Zhenfeng2
刊名COORDINATION CHEMISTRY REVIEWS
出版日期2014-07-01
卷号270页码:2-13
关键词Zirconacycle Silacycle Metallacyclobutene Zirconacyclobutene-silacyclobutene Fused Complex Coordination Skeletal Rearrangement
ISSN号0010-8545
DOI10.1016/j.ccr.2013.08.032
英文摘要Coordination-induced skeletal rearrangement of transition-metal complexes is of fundamental interest both synthetically and mechanistically. Besides commonly observed ligand substitution, the coordination of ligands may greatly alter the steric and electronic environment around the metal center, thus activating the whole compound, resulting in novel rearrangement or cleavage of chemical bonds. Subsequent formations of chemical bonds would lead to synthetically useful methods for new transition-metal complexes and organic compounds. Zirconacycles have been proved to be very useful for synthetic organic and organometallic chemistry. The present review concentrates on the coordination-induced skeletal rearrangement of zirconacyclobutene-silacyclobutene fused complexes. When treated with nitriles, alkynes, ketones, or other unsaturated organic molecules, the zirconacyclobutene-silacyclobutene fused complexes underwent the coordination-induced rearrangement and new chemical bond forming process, other than the expected direct insertion reactions. Different types of rearrangements were observed depending on the coordinating unsaturated organic molecules. A variety of zirconacycles and organic products were formed efficiently from the zirconacyclobutene-silacyclobutene fused complexes and the unsaturated organic molecules through the coordination-induced rearrangement and new chemical bond forming process. (C) 2013 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000336013800002
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/52865]  
专题中国科学院化学研究所
通讯作者Xi, Zhenfeng
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Peking Univ, Coll Chem, Minist Educ, Beijing Natl Lab Mol Sci,Key Lab Bioorgan Chem &, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes[J]. COORDINATION CHEMISTRY REVIEWS,2014,270:2-13.
APA Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes.COORDINATION CHEMISTRY REVIEWS,270,2-13.
MLA Zhao, Jing,et al."Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes".COORDINATION CHEMISTRY REVIEWS 270(2014):2-13.

入库方式: OAI收割

来源:化学研究所

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