Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes
文献类型：期刊论文
| 作者 | Zhao, Jing1; Zhang, Shaoguang2; Zhang, Wen-Xiong2; Xi, Zhenfeng2 |
| 刊名 | COORDINATION CHEMISTRY REVIEWS
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 270页码:2-13 |
| 关键词 | Zirconacycle Silacycle Metallacyclobutene Zirconacyclobutene-silacyclobutene Fused Complex Coordination Skeletal Rearrangement |
| ISSN号 | 0010-8545 |
| DOI | 10.1016/j.ccr.2013.08.032 |
| 英文摘要 | Coordination-induced skeletal rearrangement of transition-metal complexes is of fundamental interest both synthetically and mechanistically. Besides commonly observed ligand substitution, the coordination of ligands may greatly alter the steric and electronic environment around the metal center, thus activating the whole compound, resulting in novel rearrangement or cleavage of chemical bonds. Subsequent formations of chemical bonds would lead to synthetically useful methods for new transition-metal complexes and organic compounds. Zirconacycles have been proved to be very useful for synthetic organic and organometallic chemistry. The present review concentrates on the coordination-induced skeletal rearrangement of zirconacyclobutene-silacyclobutene fused complexes. When treated with nitriles, alkynes, ketones, or other unsaturated organic molecules, the zirconacyclobutene-silacyclobutene fused complexes underwent the coordination-induced rearrangement and new chemical bond forming process, other than the expected direct insertion reactions. Different types of rearrangements were observed depending on the coordinating unsaturated organic molecules. A variety of zirconacycles and organic products were formed efficiently from the zirconacyclobutene-silacyclobutene fused complexes and the unsaturated organic molecules through the coordination-induced rearrangement and new chemical bond forming process. (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336013800002 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52865]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, Zhenfeng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Beijing Natl Lab Mol Sci,Key Lab Bioorgan Chem &, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes[J]. COORDINATION CHEMISTRY REVIEWS,2014,270:2-13. |
| APA | Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes.COORDINATION CHEMISTRY REVIEWS,270,2-13. |
| MLA | Zhao, Jing,et al."Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes".COORDINATION CHEMISTRY REVIEWS 270(2014):2-13. |
入库方式： OAI收割
来源：化学研究所
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