Two new three-dimensional zinc phosphites templated by piperazine: [H(2)pip][Zn-3(HPO3)(4)(H2O)(2)] and K[H(2)pip](0.5)[Zn-3(HPO3)(4)]
文献类型：期刊论文
| 作者 | Zhang, Xiao1; Wang, Guo-Ming1; Wang, Zong-Hua1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2014-01-06 |
| 卷号 | 1056页码:25-30 |
| 关键词 | Zinc Phosphite Solvothermal Synthesis Crystal Structure Mixed Templates 12-ring Channel |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2013.10.025 |
| 英文摘要 | Two three-dimensional open-framework zinc phosphites with the same organically templated, [H(2)pip][Zn-3(HPO3)(4)(H2O)(2)] (1) and K[H(2)pip](0.5)[Zn-3(HPO3)(4)] (2) (pip = piperazine), have been solvothermally synthesized and structurally characterized by IR, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffractions. Compound 1 consists of ZnO4 tetrahedra, [HPO3] pseudopyramids and [ZnO4(H2O)(2)] octahedra, which are linked through their vertexes to generate three-dimensional architecture with intersecting 8-membered channels along the [1 0 0], [0 0 1] and [1 0 1] directions. Compound 2 is constructed from strictly alternating ZnO4 tetrahedra and [HPO3] pseudopyramids, and exhibits (3,4)-connected inorganic framework with 8-, and 12-membered channels, in which the K+ and diprotonated H(2)pip(2+) extra-framework cations reside, respectively. The coexistence of inorganic K+ and organic piperazine mixed templates in the structure is unique and, to the best of our knowledge, firstly observed in metal-phosphite materials. In addition, the participation of left-handed and right-handed helical chains in construction of the puckered 4.8(2) sheet structure in 2 is also noteworthy. (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000330147900004 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52881]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xiao,Wang, Guo-Ming,Wang, Zong-Hua,et al. Two new three-dimensional zinc phosphites templated by piperazine: [H(2)pip][Zn-3(HPO3)(4)(H2O)(2)] and K[H(2)pip](0.5)[Zn-3(HPO3)(4)][J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1056:25-30. |
| APA | Zhang, Xiao,Wang, Guo-Ming,Wang, Zong-Hua,Wang, Ying-Xia,&Lin, Jian-Hua.(2014).Two new three-dimensional zinc phosphites templated by piperazine: [H(2)pip][Zn-3(HPO3)(4)(H2O)(2)] and K[H(2)pip](0.5)[Zn-3(HPO3)(4)].JOURNAL OF MOLECULAR STRUCTURE,1056,25-30. |
| MLA | Zhang, Xiao,et al."Two new three-dimensional zinc phosphites templated by piperazine: [H(2)pip][Zn-3(HPO3)(4)(H2O)(2)] and K[H(2)pip](0.5)[Zn-3(HPO3)(4)]".JOURNAL OF MOLECULAR STRUCTURE 1056(2014):25-30. |
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来源：化学研究所
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