Reversible Transition between SDS@2 beta-CD Microtubes and Vesicles Triggered by Temperature
文献类型：期刊论文
| 作者 | Zhou, Chengcheng1,2; Cheng, Xinhao1; Yan, Yun1; Wang, Jide2; Huang, Jianbin1,2 |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2014-04-01 |
| 卷号 | 30期号:12页码:3381-3386 |
| ISSN号 | 0743-7463 |
| DOI | 10.1021/la500010p |
| 英文摘要 | Switching between association and dissociation is the well strategy for constructing responsive materials based on the host guest complexes of cyclodextrins (CDs). In this work, we report that temperature may also trigger self-assembly transition in the supramolecular system composed of sodium dodecyl sulfate (SDS) and beta-cyclodextrin (beta-CD) at a molar ratio of 1:2. We reported previously that, at this ratio, SDS and beta-CD form a channel-type SDS@2 beta-CD supramolecular unit, which further self-assembles into non-amphiphilic vesicles and microtubes driven by hydrogen bonding. Here, we report that the vesicles and microtubes can be reversibly switched between each other upon decreasing and increasing temperature. Control experiments in heavy water suggest that water molecules play a dominating role in the hydrogen bonding between SDS@2 beta-CD supramolecular units at lower concentration and higher temperature. Under opposite conditions, the hydrogen bonding between CDs is dominating. Therefore, for the 5% system, we observed a vesicle to microtube transition with a decreasing temperature, whereas for the 10% system, we observed the reverse process. Both processes are reversible. This is not only an example of temperature-triggered responsiveness in non-amphiphilic self-assemblies but also a new mode of responsiveness for the host guest inclusion systems based on CDs. This temperature-responsive process is anticipated to shed light on the design and development of novel advanced materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000333776400012 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53033]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Yun |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100871, Peoples R China 2.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Chengcheng,Cheng, Xinhao,Yan, Yun,et al. Reversible Transition between SDS@2 beta-CD Microtubes and Vesicles Triggered by Temperature[J]. LANGMUIR,2014,30(12):3381-3386. |
| APA | Zhou, Chengcheng,Cheng, Xinhao,Yan, Yun,Wang, Jide,&Huang, Jianbin.(2014).Reversible Transition between SDS@2 beta-CD Microtubes and Vesicles Triggered by Temperature.LANGMUIR,30(12),3381-3386. |
| MLA | Zhou, Chengcheng,et al."Reversible Transition between SDS@2 beta-CD Microtubes and Vesicles Triggered by Temperature".LANGMUIR 30.12(2014):3381-3386. |
入库方式： OAI收割
来源：化学研究所
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