中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Phosphonate-Functionalized Donor Polymer as an Underlying Interlayer To Improve Active Layer Morphology in Polymer Solar Cells

文献类型:期刊论文

作者Meng, Bin1,2; Fu, Yingying1; Xie, Zhiyuan1; Liu, Jun1; Wang, Lixiang1
刊名MACROMOLECULES
出版日期2014-09-23
卷号47期号:18页码:6246-6251
ISSN号0024-9297
DOI10.1021/ma5008754
英文摘要A novel polymer is developed and used as underlying interlayer to improve donor polymer/acceptor material blend morphology of active layer in polymer solar cells (PSCs). The polymer poly{N-9-[1,17-bis-(diethylphosphonate)heptadecanyl]-2,7-carbazole-alt-5,5-(4,7-di-2-thienyl-2,1,3-benzothiadiazole)} (PCDTBT-Pho) is designed by attaching polar phosphonate moieties to the side chain of the donor polymer, poly[N-9-heptadecanyl-2,7-carbazole-alt-5,5-(4,7-di-2-thienyl-2,1,3-benzothiadiazole)] (PCDTBT). The pendant phosphonate moieties lead to different solubility and proper surface energy of PCDTBT-Pho. As a result, in PSC devices, the underlying PCDTBT-Pho layer facilitates the formation of biscontinuous network morphology in the active layer, makes the donor polymer enriched at the anode side, and induces the donor polymer to crystallize. These improvements contribute to improved charge separation and transport, leading to short-circuit current density enhancement by 12% and power conversion efficiency enhancement by 8% of the PSC devices. Thus, the design and application of PCDTBT-Pho indicate a novel approach to optimize active layer morphology and improve photovoltaic efficiency of PSCs.
语种英语
WOS记录号WOS:000342184700012
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/53059]  
专题中国科学院化学研究所
通讯作者Liu, Jun
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Meng, Bin,Fu, Yingying,Xie, Zhiyuan,et al. Phosphonate-Functionalized Donor Polymer as an Underlying Interlayer To Improve Active Layer Morphology in Polymer Solar Cells[J]. MACROMOLECULES,2014,47(18):6246-6251.
APA Meng, Bin,Fu, Yingying,Xie, Zhiyuan,Liu, Jun,&Wang, Lixiang.(2014).Phosphonate-Functionalized Donor Polymer as an Underlying Interlayer To Improve Active Layer Morphology in Polymer Solar Cells.MACROMOLECULES,47(18),6246-6251.
MLA Meng, Bin,et al."Phosphonate-Functionalized Donor Polymer as an Underlying Interlayer To Improve Active Layer Morphology in Polymer Solar Cells".MACROMOLECULES 47.18(2014):6246-6251.

入库方式: OAI收割

来源:化学研究所

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