Metal (cadmium and manganese)-mediated assemblies of two acetohydrazide zinc porphyrins for use in supramolecular solar cells
文献类型：期刊论文
| 作者 | Cao, Jing1; Hu, Dong-Cheng1; Liu, Jia-Cheng1; Li, Ren-Zhi2; Jin, Neng-Zhi3 |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2014-04-01 |
| 卷号 | 414页码:165-169 |
| 关键词 | Self-assembly Zinc Porphyrin Solar Cell |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2014.01.052 |
| 英文摘要 | In this work, a metal-mediated assembling strategy has been used to construct four assemblies (ZnPx=M-A) with two acetohydrazide zinc porphyrins bearing two different donor groups (ZnPx, benzimidazyl unit for ZnP1, phenol group for ZnP2) appended (E)-4-[(pyridin-4-ylmethylene) amino] benzoic acid ligands (A), in which the metal ions (M, M = Cd2+ and Mn2+) are used to bridge the ZnPx and A units, resulting in a ZnPx-M-A organized mode. Further, these assemblies were immobilized on the semiconducting TiO2 electrode surfaces by the carboxylic groups of A units, and their photovoltaic performances were performed under irradiance of 100 mW cm (2) AM 1.5G sunlight. The assembled structures were characterized by transmission electron microscopy (TEM), computational calculations and energy-dispersive X-ray spectroscopy (EDX). Photoelectrochemical studies reveal a significantly improved photovoltaic performance for ZnP2-Mn-A compared to other assemblies, which are also reflected by their corresponding UV-Vis absorption, fluorescence spectra and HOMO-LUMO energy gaps. (C) 2014 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000334311700026 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53071]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hu, Dong-Cheng |
| 作者单位 | 1.Northwest Normal Univ, Coll Chem & Chem Engn,Key Lab Ecoenvironm Related, Key Lab Bioelectrochem & Environm Anal Gansu Prov, Key Lab Polymer Mat Gansu Prov,Minist Edu, Lanzhou 730070, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Gansu Comp Ctr, Lanzhou 730030, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Jing,Hu, Dong-Cheng,Liu, Jia-Cheng,et al. Metal (cadmium and manganese)-mediated assemblies of two acetohydrazide zinc porphyrins for use in supramolecular solar cells[J]. INORGANICA CHIMICA ACTA,2014,414:165-169. |
| APA | Cao, Jing,Hu, Dong-Cheng,Liu, Jia-Cheng,Li, Ren-Zhi,&Jin, Neng-Zhi.(2014).Metal (cadmium and manganese)-mediated assemblies of two acetohydrazide zinc porphyrins for use in supramolecular solar cells.INORGANICA CHIMICA ACTA,414,165-169. |
| MLA | Cao, Jing,et al."Metal (cadmium and manganese)-mediated assemblies of two acetohydrazide zinc porphyrins for use in supramolecular solar cells".INORGANICA CHIMICA ACTA 414(2014):165-169. |
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来源：化学研究所
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