Direct Borylation of Primary C-H Bonds in Functionalized Molecules by Palladium Catalysis
文献类型：期刊论文
| 作者 | Zhang, Li-Sheng1,2,3; Chen, Guihua1,2,3; Wang, Xin1,2,3; Guo, Qing-Yun1,2,3; Zhang, Xi-Sha1,2,3; Pan, Fei1,2,3; Chen, Kang1,2,3; Shi, Zhang-Jie1,2,3,4 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014-04-07 |
| 卷号 | 53期号:15页码:3899-3903 |
| 关键词 | Amino Acids Borylation Ch Functionalization Directing Groups Palladium |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201310000 |
| 英文摘要 | Organoborane compounds are among the most commonly employed intermediates in organic synthesis and serve as crucial precursors to alcohols, amines, and various functionalized molecules. A simple palladium-based system catalyzes the conversion of primary C(sp(3))H bonds in functionalized complex organic molecules into alkyl boronate esters. Amino acids, amino alcohols, alkyl amines, and a series of bioactive molecules can be functionalized with the use of readily available and removable directing groups in the presence of commercially available additives, simple ligands, and oxygen (O-2) as the terminal oxidant. This approach represents an economic and environmentally friendly method that could find broad applications. |
| 语种 | 英语 |
| WOS记录号 | WOS:000333634800021 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53081]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Zhang-Jie |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Minist Educ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China 4.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Li-Sheng,Chen, Guihua,Wang, Xin,et al. Direct Borylation of Primary C-H Bonds in Functionalized Molecules by Palladium Catalysis[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(15):3899-3903. |
| APA | Zhang, Li-Sheng.,Chen, Guihua.,Wang, Xin.,Guo, Qing-Yun.,Zhang, Xi-Sha.,...&Shi, Zhang-Jie.(2014).Direct Borylation of Primary C-H Bonds in Functionalized Molecules by Palladium Catalysis.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(15),3899-3903. |
| MLA | Zhang, Li-Sheng,et al."Direct Borylation of Primary C-H Bonds in Functionalized Molecules by Palladium Catalysis".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.15(2014):3899-3903. |
入库方式： OAI收割
来源：化学研究所
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