Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry
文献类型：期刊论文
| 作者 | Geng, Weizhi1,2; Wei, Junnian1,2; Zhang, Wen-Xiong1,2; Xi, Zhenfeng1,2,3 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2014-01-15 |
| 卷号 | 136期号:2页码:610-613 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja4114243 |
| 英文摘要 | Four types of alkenyl organocopper(I) aggregates linked by 1,3-butadienyl and/or 1,3,5,7-octatetraenyl moieties were selectively realized in good isolated yields. All these organocopper(I) aggregates were structurally characterized by single-crystal X-ray structural analysis. These unprecedented aggregates, stabilized by multiple Cu-Cu interactions and the conjugated 1,3-butadienyl or 1,3,5,7-octatetraenyl bridges, could undergo controlled structural transformations. The 1,4-dicopper 1,3-butadienyl aggregate 3 could be efficiently transformed to aggregate 2, while LiI could disaggregate the 1,3-butadienyl-1,3,5,7-octatetraenyl aggregate 4 to 1,3,5,7-octatetraenyl aggregate 5 and 1,3-butadienyl aggregate 2. Preliminary reaction chemistry and synthetic applications of these organocopper(I) aggregates were also investigated. |
| 语种 | 英语 |
| WOS记录号 | WOS:000330018600018 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53123]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, Zhenfeng |
| 作者单位 | 1.Peking Univ, BNLMS, Coll Chem, Beijing 100871, Peoples R China 2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Minist Educ, Beijing 100871, Peoples R China 3.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Geng, Weizhi,Wei, Junnian,Zhang, Wen-Xiong,et al. Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(2):610-613. |
| APA | Geng, Weizhi,Wei, Junnian,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(2),610-613. |
| MLA | Geng, Weizhi,et al."Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.2(2014):610-613. |
入库方式： OAI收割
来源：化学研究所
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