The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst
文献类型：期刊论文
| 作者 | Zhang, Peng; Wu, Tianbin; Hou, Minqiang; Ma, Jun; Liu, Huizhen; Jiang, Tao; Wang, Weitao; Wu, Congyi; Han, Buxing |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2014-12-01 |
| 卷号 | 6期号:12页码:3323-3327 |
| 关键词 | Arenes Hydrogenation Lewis Acids Palladium Surface Hydroxyl Groups |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.201402671 |
| 英文摘要 | Al2O3 or SiO2 particles with abundant surface hydroxyl groups can prevent side reactions of aromatic compounds with AlCl3 completely; this Lewis acid can potentially destroy the stable structure of aromatic compounds to a large extent. This discovery was successfully utilized in the highly efficient hydrogenation of benzene, toluene, and naphthalene under mild conditions co-catalyzed by AlCl3 and Pd/Al2O3 or Pd/SiO2. Pd, AlCl3, and the surface hydroxyl groups on the support show excellent cooperative effects for the hydrogenation reactions. Theoretical studies indicate that formation of a complex, by an interaction between benzene, AlCl3, and the solid oxides, plays a key role in the highly efficient hydrogenation reactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000345975300007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53241]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, Tianbin |
| 作者单位 | Chinese Acad Sci, CAS Key Lab Colloid & Interface & Thermodynam, Inst Chem, BNLMS, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Peng,Wu, Tianbin,Hou, Minqiang,et al. The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst[J]. CHEMCATCHEM,2014,6(12):3323-3327. |
| APA | Zhang, Peng.,Wu, Tianbin.,Hou, Minqiang.,Ma, Jun.,Liu, Huizhen.,...&Han, Buxing.(2014).The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst.CHEMCATCHEM,6(12),3323-3327. |
| MLA | Zhang, Peng,et al."The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst".CHEMCATCHEM 6.12(2014):3323-3327. |
入库方式： OAI收割
来源：化学研究所
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