Low-Dose Imidazolium Cation Grafted Polymeric Nanotubes for Quasi-solid-state Dye-sensitized Solar Cells
文献类型:期刊论文
作者 | Wang, Lei1; Qiu, Lihua1; Yang, Zhenzhong2![]() |
刊名 | ELECTROCHIMICA ACTA
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出版日期 | 2014-07-01 |
卷号 | 133页码:446-452 |
关键词 | Polymeric Nanotubes Quasi-solid-state Electrolytes Dye-sensitized Solar Cells Stability |
ISSN号 | 0013-4686 |
DOI | 10.1016/j.electacta.2014.04.124 |
英文摘要 | Poly(divinybenzene-co-chloromethylstyrene) (poly(DVB-co-VBC)) nanotubes (PDVBVBC-NT) and imidazolium surface functionalized poly(DVB-co-VBC) (Im-PDVBVBC-NT) are synthesized by cationic polymerization and utilized as the gelators for ionic liquid based gel electrolytes. Compared with the synthesized pristine PDVBVBC-NT, Im-PDVBVBC-NT (a gelator dose as low as 1 wt%) based gel electrolytes show higher ionic conductivity and diffusion coefficient. The fabricated DSSCs based on Im-PDVBVBC-NT gel electrolyte show a power conversion efficiency of 4.9% and 5.5% under a simulated air mass 1.5 solar spectrum illumination at 100 mW cm(-2) and 50 mW cm(-2), respectively. Furthermore, Im-PDVBVBC-NT based DSSCs show better long-term stability than that with ionic liquid electrolyte, which indicated that Im-PDVBVBC-NT based gel electrolytes could overcome the leakage problems of the cells with pure ionic liquid electrolytes. (C) 2014 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000337985800056 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/53245] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yang, Zhenzhong |
作者单位 | 1.Soochow Univ, Dept Polymer Sci & Engn, Coll Chem Chem Engn & Mat Sci, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Lei,Qiu, Lihua,Yang, Zhenzhong,et al. Low-Dose Imidazolium Cation Grafted Polymeric Nanotubes for Quasi-solid-state Dye-sensitized Solar Cells[J]. ELECTROCHIMICA ACTA,2014,133:446-452. |
APA | Wang, Lei,Qiu, Lihua,Yang, Zhenzhong,&Yan, Feng.(2014).Low-Dose Imidazolium Cation Grafted Polymeric Nanotubes for Quasi-solid-state Dye-sensitized Solar Cells.ELECTROCHIMICA ACTA,133,446-452. |
MLA | Wang, Lei,et al."Low-Dose Imidazolium Cation Grafted Polymeric Nanotubes for Quasi-solid-state Dye-sensitized Solar Cells".ELECTROCHIMICA ACTA 133(2014):446-452. |
入库方式: OAI收割
来源:化学研究所
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