Influences of hyperbranched polyethylenimine on the reactive compatibilization of polycarbonate/polyamide blends
文献类型：期刊论文
| 作者 | Wang, Ming-ji1,2; Yuan, Guang-cui1; Han, Charles C.1 |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2015-04-01 |
| 卷号 | 33期号:4页码:652-660 |
| 关键词 | Polyamide Polycarbonate Polyethylenimine Blend Reactive Compatibilization |
| ISSN号 | 0256-7679 |
| DOI | 10.1007/s10118-014-1475-0 |
| 英文摘要 | The influences of hyperbranched polyethylenimine (hPEI), which possesses many reactive amino end-groups, on the blending properties of bisphenol-A polycarbonate (PC) and amorphous polyamide (aPA) were systematically investigated. Scanning electron microscopy (SEM) and differential scanning calorimetry (DSC) were used to observe the effect of hPEI on morphologies of PC and aPA phases in bulk blends. While the interfacial fracture toughness between planar PC and aPA layers with and without hPEI was studied by using augmented double cantilever beam (ADCB) method. Results show that the compatibility in PC/aPA blends can be significantly improved by adding a small amount of hPEI, mainly due to the interchange reactions between the polymers leading to the formation of block copolymers, cross-linked polymers and molecules with other constitutions. The augmented double cantilever beam experiments showed that the reactive process drastically reinforced the interfacial adhesion between planar layers of PC and aPA. However, degradation takes place during annealing at 180 A degrees C, which was responsible for the production of small molar mass species of PC. |
| 语种 | 英语 |
| WOS记录号 | WOS:000349763500013 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53325]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, Guang-cui |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem,Joint Lab Polym, Beijing 100190, Peoples R China 2.Jinan Shengquan Grp Co Ltd, Inst Phenol Resin, Jinan 250204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ming-ji,Yuan, Guang-cui,Han, Charles C.. Influences of hyperbranched polyethylenimine on the reactive compatibilization of polycarbonate/polyamide blends[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2015,33(4):652-660. |
| APA | Wang, Ming-ji,Yuan, Guang-cui,&Han, Charles C..(2015).Influences of hyperbranched polyethylenimine on the reactive compatibilization of polycarbonate/polyamide blends.CHINESE JOURNAL OF POLYMER SCIENCE,33(4),652-660. |
| MLA | Wang, Ming-ji,et al."Influences of hyperbranched polyethylenimine on the reactive compatibilization of polycarbonate/polyamide blends".CHINESE JOURNAL OF POLYMER SCIENCE 33.4(2015):652-660. |
入库方式： OAI收割
来源：化学研究所
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