Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports
文献类型：期刊论文
| 作者 | Kang, Xinchen1; Shang, Wenting1; Zhu, Qinggong1; Zhang, Jianling1; Jiang, Tao1; Han, Buxing1; Wu, Zhonghua2; Li, Zhihong2; Xing, Xueqing2 |
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:3页码:1668-1675 |
| ISSN号 | 2041-6520 |
| DOI | 10.1039/c4sc03736g |
| 英文摘要 | We proposed a strategy to synthesize mesoporous inorganic salt particles using the special properties of ionic liquid (IL) mixtures, and hollow mesoporous LaF3, NdF3, and YF3 particles were synthesized and characterized using different techniques. The size of the mesopores in the salt particles was about 4 nm, and the materials were full of crystal defects. The LaF3, NdF3 and YF3 particles were used as the catalysts for the cyanosilylation reaction of benzaldehyde using trimethylsilyl cyanide, and Ru/LaF3 and Ru/NdF3, in which Ru nanocatalysts were supported on the LaF3 and NdF3 particles with mesopores, were used to catalyze hydrogenations of benzene to cyclohexane and levulinic acid (LA) to g-valerolactone (GVL). It was discovered that the activities of these catalysts were unprecedentedly high for these reactions. Detailed study showed that both the crystal defects and the mesopores in the salt particles played crucial roles for the extremely high catalytic activity. |
| 语种 | 英语 |
| WOS记录号 | WOS:000349832600008 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53339]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Colloid & Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Xinchen,Shang, Wenting,Zhu, Qinggong,et al. Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports[J]. CHEMICAL SCIENCE,2015,6(3):1668-1675. |
| APA | Kang, Xinchen.,Shang, Wenting.,Zhu, Qinggong.,Zhang, Jianling.,Jiang, Tao.,...&Xing, Xueqing.(2015).Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports.CHEMICAL SCIENCE,6(3),1668-1675. |
| MLA | Kang, Xinchen,et al."Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports".CHEMICAL SCIENCE 6.3(2015):1668-1675. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。