Realizing over 10% efficiency in polymer solar cell by device optimization
文献类型:期刊论文
作者 | Zhang, Shaoqing1,2; Ye, Long1; Zhao, Wenchao1; Yang, Bei1; Wang, Qi1,2; Hou, Jianhui1,2 |
刊名 | SCIENCE CHINA-CHEMISTRY
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出版日期 | 2015-02-01 |
卷号 | 58期号:2页码:248-256 |
关键词 | Polymer Solar Cells Photovoltaic Polymer Device Optimization Solvent Additives |
ISSN号 | 1674-7291 |
DOI | 10.1007/s11426-014-5273-x |
英文摘要 | The low band gap polymer based on benzodithiophene (BDT)-thieno[3,4-b]thiophene (TT) backbone, PBDT-TS1, was synthesized following our previous work and the bulk heterojunction (BHJ) material comprising PBDT-TS1/PC71BM was optimized and characterized. By processing the active layer with different additives i.e. 1,8-diiodooctane (DIO), 1-chloronaphthalene (CN) and 1, 8-octanedithiol (ODT) and optimizing the ratio of each additive in the host solvent, a high PCE of 9.98% was obtained under the condition of utilizing 3% DIO as processing additive in CB. The effect of varied additives on photovoltaic performance was illustrated with atomic force microscopy (AFM) and transmission electron microscope (TEM) measurements that explained changes in photovoltaic parameters. These results provide valuable information of solvent additive choice in device optimization of PBDTTT polymers, and the systematic device optimization could be applied in other efficient photovoltaic polymers. Apparently, this work presents a great advance in single junction PSCs, especially in PSCs with conventional architecture. |
语种 | 英语 |
WOS记录号 | WOS:000349001500010 |
出版者 | SCIENCE PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/53349] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Hou, Jianhui |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Shaoqing,Ye, Long,Zhao, Wenchao,et al. Realizing over 10% efficiency in polymer solar cell by device optimization[J]. SCIENCE CHINA-CHEMISTRY,2015,58(2):248-256. |
APA | Zhang, Shaoqing,Ye, Long,Zhao, Wenchao,Yang, Bei,Wang, Qi,&Hou, Jianhui.(2015).Realizing over 10% efficiency in polymer solar cell by device optimization.SCIENCE CHINA-CHEMISTRY,58(2),248-256. |
MLA | Zhang, Shaoqing,et al."Realizing over 10% efficiency in polymer solar cell by device optimization".SCIENCE CHINA-CHEMISTRY 58.2(2015):248-256. |
入库方式: OAI收割
来源:化学研究所
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