中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Construction of thermally stable 3,6-disubstituted spiro-fluorene derivatives as host materials for blue phosphorescent organic light-emitting diodes

文献类型:期刊论文

作者Wang, Lei1; Pan, Biao1; Zhu, Liping2; Wang, Bo1; Wang, Yixing1; Liu, Yakun1; Jin, Jiangjiang1; Chen, Jiangshan2; Ma, Dongge2
刊名DYES AND PIGMENTS
出版日期2015-03-01
卷号114页码:222-230
关键词High Triplet Energy High T-g Blue Phosphorescent Organic Light-emitting Device Host Materials Low Roll-off 3 6-spirobifluorene
ISSN号0143-7208
DOI10.1016/j.dyepig.2014.11.011
英文摘要Four novel thermally stable host materials, 9,9'-(9,9-diphenyl-9H-fluorene-3,6-diyl)bis(9H-carbazole) (BBDC), 3-(3,6-bis(diphenylphosphoryl)-9,9-diphenylfluorene (BBDP), 3,6-di(9H-carbazol-9-yl)-9,9'-spirobi[fluorene] (BSBDC), 3,6-di(9H-carbazol-9-yl)-9,9'-spirobi[fluorene] (BSBDP) were designed and synthesized by linking phosphine oxide or carbazole moieties to the 3,6-position of a spirofluorene core. In comparison to the conventional 2,7-disubstituted homologues, 3,6-disubstituted spiro-fluorene can offer more versatile and advanced properties in terms of higher triplet energy (>2.8 eV) and higher glass-transition temperatures (ca. 215 degrees C). Accordingly, doped blue-emitting devices were fabricated and the device with BSBDP as host exhibited a very low turn-on voltage of 2.8 V and maximum current efficiency of 34.2 cd A(-1), external quantum efficiency of 18.7% and power efficiency of 34.4 lm W-1. These results demonstrate that 3,6-disubstituted spiro-fluorene derivatives are promising host materials for blue phosphorescent organic light-emitting devices (PhOLEDs). (C) 2014 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000348953400029
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/53415]  
专题中国科学院化学研究所
通讯作者Wang, Lei
作者单位1.Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Wang, Lei,Pan, Biao,Zhu, Liping,et al. Construction of thermally stable 3,6-disubstituted spiro-fluorene derivatives as host materials for blue phosphorescent organic light-emitting diodes[J]. DYES AND PIGMENTS,2015,114:222-230.
APA Wang, Lei.,Pan, Biao.,Zhu, Liping.,Wang, Bo.,Wang, Yixing.,...&Ma, Dongge.(2015).Construction of thermally stable 3,6-disubstituted spiro-fluorene derivatives as host materials for blue phosphorescent organic light-emitting diodes.DYES AND PIGMENTS,114,222-230.
MLA Wang, Lei,et al."Construction of thermally stable 3,6-disubstituted spiro-fluorene derivatives as host materials for blue phosphorescent organic light-emitting diodes".DYES AND PIGMENTS 114(2015):222-230.

入库方式: OAI收割

来源:化学研究所

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