Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels
文献类型：期刊论文
| 作者 | Wang, Guo-Ming1; Li, Jin-Hua1; Gao, Cui-Li1; Zhang, Jun-Cheng1; Zhang, Xiao1; Bao, Zhen-Zhen1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2015 |
| 卷号 | 39页码:1-5 |
| 关键词 | Open Framework Zinc Phosphate 16-ring Channels Hybrid Luminescence |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2014.11.007 |
| 英文摘要 | A novel inorganic-organic hybrid open-framework zinc phosphate, (NH4)[Zn-3(PO4)(3)(HPO4)(2)(HAPIM)(2)]center dot(H2O) (1), was solvothermally synthesized in the presence of 1-(3-aminopropyl)imidazole (APIM) as structure-directing agent. Its structure is built up by the alternate linkages between ZnO4, ZnO3N, PO4 and HPO4 tetrahedral moieties, forming an unusual three-dimensional framework with intersecting 8-, 10-, and 16-ring channels. The arrangement of the monoprotonated APIM molecules in 1 is unique and they play dual roles as both ligands and countercations. It is the first example with APIM as template in extra-large-channel structures in zincophosphates. The framework contains a Zn/P ratio of 1:1 and exhibits remarkable low framework density. Photoluminescence studies show that there is a ligand-to-metal charge transfer. (C) 2014 Published by Elsevier Masson SAS. |
| 语种 | 英语 |
| WOS记录号 | WOS:000348952700001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53441]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Coll Phys Sci, Coll Chem Sci & Engn, Teachers Coll, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Guo-Ming,Li, Jin-Hua,Gao, Cui-Li,et al. Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels[J]. SOLID STATE SCIENCES,2015,39:1-5. |
| APA | Wang, Guo-Ming.,Li, Jin-Hua.,Gao, Cui-Li.,Zhang, Jun-Cheng.,Zhang, Xiao.,...&Lin, Jian-Hua.(2015).Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels.SOLID STATE SCIENCES,39,1-5. |
| MLA | Wang, Guo-Ming,et al."Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels".SOLID STATE SCIENCES 39(2015):1-5. |
入库方式： OAI收割
来源：化学研究所
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