Effect of electron-withdrawing units on triphenylamine-based small molecules for solution-processed organic solar cells
文献类型：期刊论文
| 作者 | Wang, Yifan1,3; Bai, Huitao1; Cheng, Pei1,3; Zhang, Mingyu2; Zhan, Xiaowei2 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2015-02-01 |
| 卷号 | 58期号:2页码:331-338 |
| 关键词 | Organic Solar Cell Small Molecule Triphenylamine Electron-withdrawing Unit |
| ISSN号 | 1674-7291 |
| DOI | 10.1007/s11426-014-5217-5 |
| 英文摘要 | Organic small molecules (TPA-BT3T, TPA-PT3T, and TPA-DFBT3T) using triphenylamine as a donor unit, terthiophene as a bridge, and benzo-2,1,3-thiadiazole (BT), [1,2,5]thiadiazolo[3,4-c]pyridine (PT) or 5,6-difluorobenzo[c][1,2,5]thiadiazole (DFBT) as an acceptor unit were designed and synthesized through Suzuki coupling reactions. These molecules exhibited good thermal stability with decomposition temperatures over 380 A degrees C and broad absorption from 300 to 700 nm. Photovoltaic devices were fabricated with these small molecules as donors and PC71BM as an acceptor. The TPA-BT3T based devices exhibited a power conversion efficiency of 2.89%, higher than those of the TPA-PT3T- and TPA-DFBT3T-based devices (1.34% and 1.54% respectively). The effects of electron-withdrawing units on absorption, energy level, charge transport, morphology, and photovoltaic properties also were investigated. |
| 语种 | 英语 |
| WOS记录号 | WOS:000349001500020 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53453]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, Xiaowei |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 2.Peking Univ, Dept Mat Sci & Engn, Coll Engn, Beijing 100871, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yifan,Bai, Huitao,Cheng, Pei,et al. Effect of electron-withdrawing units on triphenylamine-based small molecules for solution-processed organic solar cells[J]. SCIENCE CHINA-CHEMISTRY,2015,58(2):331-338. |
| APA | Wang, Yifan,Bai, Huitao,Cheng, Pei,Zhang, Mingyu,&Zhan, Xiaowei.(2015).Effect of electron-withdrawing units on triphenylamine-based small molecules for solution-processed organic solar cells.SCIENCE CHINA-CHEMISTRY,58(2),331-338. |
| MLA | Wang, Yifan,et al."Effect of electron-withdrawing units on triphenylamine-based small molecules for solution-processed organic solar cells".SCIENCE CHINA-CHEMISTRY 58.2(2015):331-338. |
入库方式： OAI收割
来源：化学研究所
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