Self-assembly of highly dispersed Pt and PtRu nanoparticles on perylene diimide derivatives functionalized carbon nanotubes as enhanced catalysts for methanol electro-oxidation
文献类型：期刊论文
| 作者 | Yang, Xiulin1,2; Liu, Xianzong1,2; Meng, Xiangyue1,2; Wang, Xueyun1,2; Li, Gen1,2; Shu, Chunying1; Jiang, Li1; Wang, Chunru1 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2013-10-15 |
| 卷号 | 240页码:536-543 |
| 关键词 | Self-assembly Perylene Diimide Carbon Nanotubes Electrocatalysis Fuel Cells |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2013.04.084 |
| 英文摘要 | Both narrow size and highly homogeneous distribution of Pt and PtRu nanoparticles (NPs) are achieved on multi-walled carbon nanotubes functionalized by perylene diimide derivatives (PD-CNTs) using ethylene glycol as reducing agents. FT-IR and UV-visible spectrum illustrate that the PA molecule has been successfully transformed into PD molecule and modified on the surface of CNTs. TEM images show that a multilayer of the PD moiety is formed on CNT surface followed by the uniform deposition of Pt and PtRu NPs through self-assembly. The resulting Pt and PtRu NPs on PD-CNTs exhibit competitively catalytic activity for methanol electro-oxidation and outstanding CO-tolerance properties compared to PtRu NPs on acid-oxidized CNTs (AO-CNTs) and carbon black. Furthermore, the PD-CNT based catalysts are also much more stable than PtRu/AO-CNTs through long-term cycle stability testing. The proposed synthesis route provides a facile, feasible and effective method for developing highly efficient electrocatalysts. 2013 (C) Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000321803700066 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53677]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Li |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xiulin,Liu, Xianzong,Meng, Xiangyue,et al. Self-assembly of highly dispersed Pt and PtRu nanoparticles on perylene diimide derivatives functionalized carbon nanotubes as enhanced catalysts for methanol electro-oxidation[J]. JOURNAL OF POWER SOURCES,2013,240:536-543. |
| APA | Yang, Xiulin.,Liu, Xianzong.,Meng, Xiangyue.,Wang, Xueyun.,Li, Gen.,...&Wang, Chunru.(2013).Self-assembly of highly dispersed Pt and PtRu nanoparticles on perylene diimide derivatives functionalized carbon nanotubes as enhanced catalysts for methanol electro-oxidation.JOURNAL OF POWER SOURCES,240,536-543. |
| MLA | Yang, Xiulin,et al."Self-assembly of highly dispersed Pt and PtRu nanoparticles on perylene diimide derivatives functionalized carbon nanotubes as enhanced catalysts for methanol electro-oxidation".JOURNAL OF POWER SOURCES 240(2013):536-543. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。