The structural details and substituent effects on biphenyls adlayers with halogen/pseudohalogen substituents on Au(111): An STM investigation
文献类型：期刊论文
| 作者 | Cui, Bo1,2,3; Yan, Hui-Juan1,2; Wang, Dong1,2; Wan, Li-Jun1,2 |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 688页码:237-242 |
| 关键词 | Halogen/pseudohalogen-terminated Biphenyls Electrochemical Scanning Tunneling Microscopy Au(111) Electrode |
| ISSN号 | 1572-6657 |
| DOI | 10.1016/j.jelechem.2012.06.014 |
| 英文摘要 | The substituent effect on the adsorption behaviors of four halogen/pseudohalogen-terminated biphenyls (X-BP-X, with X = F, Br, land CN) on a Au(111) surface in 0.1 M HClO4 solution has been investigated by electrochemical scanning tunneling microscopy (ECSTM) and cyclic voltammetry (CV). All the four molecules could form ordered adlayers at adsorption potentials. From F-BP-F, Br-BP-Br to I-BP-I, the molecular adsorption configuration varies from upright, alternating upright and flat-lying to totally flat-lying. In contrast, a trimer motif connected via CN-Au coordination interaction is found as the building unit for the adlayer of CN-BP-CN on Au(111) electrode. The adlayer structures and configurations are regulated by the properties of the substituted groups. (C) 2012 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317158800037 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53819]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Bo,Yan, Hui-Juan,Wang, Dong,et al. The structural details and substituent effects on biphenyls adlayers with halogen/pseudohalogen substituents on Au(111): An STM investigation[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2013,688:237-242. |
| APA | Cui, Bo,Yan, Hui-Juan,Wang, Dong,&Wan, Li-Jun.(2013).The structural details and substituent effects on biphenyls adlayers with halogen/pseudohalogen substituents on Au(111): An STM investigation.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,688,237-242. |
| MLA | Cui, Bo,et al."The structural details and substituent effects on biphenyls adlayers with halogen/pseudohalogen substituents on Au(111): An STM investigation".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 688(2013):237-242. |
入库方式： OAI收割
来源：化学研究所
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