Selective oxygenation of olefins with hydrogen peroxide catalyzed by iron(II) bipyridine complex included in NaY zeolite under visible light irradiation
文献类型：期刊论文
| 作者 | Ren, Yanjun1,3; Ma, Wanhong1; Che, Yanke1; Hu, Xuefeng1; Zhang, Xinzhi1; Qian, Xinhua2; Birney, David M.4 |
| 刊名 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
 |
| 出版日期 | 2013-08-15 |
| 卷号 | 266页码:22-27 |
| 关键词 | Olefins Iron Bipyridine Zeolite Hydrogen Peroxide Photooxidation |
| ISSN号 | 1010-6030 |
| DOI | 10.1016/j.jphotochem.2013.05.018 |
| 英文摘要 | A novel visible light photocatalyst of iron(II) bipyridine complex encapsulated within NaY zeolite for selective oxygenation of styrene with high turnover (1800) and high benzaldehyde selectivity (86%) using hydrogen peroxide as the oxidant under ambient conditions was explored. This photocatalyst was also effective for the oxidation of other olefins, such as 4-cyanostyrene, 4-methoxystyrene, 3-methylstyrene, 1,1-diphenylethylene, cis-stilbene, trans-stilbene, trans-beta-methylstyrene, alpha-methylstyrene, triphenylethylene, 1-octene, 2-octene, cyclohexene and cyclooctene, into the corresponding aldehydes, ketones or olefin oxides. The study shows that the photooxygenation of styrene occurs within the supercages of zeolite Y, the products benzaldehyde and formaldehyde escape into the solution after reaction, leading to high turnovers. Based on the experimental results, the photooxidation mechanism is also discussed. (c) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322352600004 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53845]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ren, Yanjun |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100080, Peoples R China 2.PetroChina Co Ltd, Fushun Petrochem Co, Fushun 113008, Liaoning, Peoples R China 3.Chinese Res Inst Environm Sci, Beijing 100012, Peoples R China 4.Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA |
| 推荐引用方式 GB/T 7714 | Ren, Yanjun,Ma, Wanhong,Che, Yanke,et al. Selective oxygenation of olefins with hydrogen peroxide catalyzed by iron(II) bipyridine complex included in NaY zeolite under visible light irradiation[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2013,266:22-27. |
| APA | Ren, Yanjun.,Ma, Wanhong.,Che, Yanke.,Hu, Xuefeng.,Zhang, Xinzhi.,...&Birney, David M..(2013).Selective oxygenation of olefins with hydrogen peroxide catalyzed by iron(II) bipyridine complex included in NaY zeolite under visible light irradiation.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,266,22-27. |
| MLA | Ren, Yanjun,et al."Selective oxygenation of olefins with hydrogen peroxide catalyzed by iron(II) bipyridine complex included in NaY zeolite under visible light irradiation".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 266(2013):22-27. |
入库方式： OAI收割
来源：化学研究所
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