New emissive organic molecule based on pyrido[3,4-g]isoquinoline framework: synthesis and fluorescence tuning as well as optical waveguide behavior
文献类型：期刊论文
| 作者 | Wang, Jianguo; Zhang, Guanxin1; Liu, Zitong; Gu, Xingui; Yan, Yongli; Zhang, Chuang; Xu, Zhenzhen; Zhao, Yongsheng; Fu, Hongbing; Zhang, Deqing |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2013-04-01 |
| 卷号 | 69期号:13页码:2687-2692 |
| 关键词 | Isoquinoline Solid-state Emission Fluorescence Tuning Optical Waveguide |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2013.02.041 |
| 英文摘要 | In this paper we report the synthesis and crystal structures of emissive organic molecule (la) based on pyrido[3,4-g]isoquinoline framework as well as its isomers 1b and 1c. The emission quantum yields decrease after transformation of pyridine moieties in la into the cyclic-amides in 1b and 1c. The fluorescent spectral results reveal that la, 1b, and 1c exhibit no AIE behavior. This is tentatively attributed to intramolecular weak C center dot center dot center dot H interactions, which may impede the intramolecular rotations based on the crystal structures of la and 1c. Interestingly, 1a, 1b, and 1c are emissive in the solid state, and among them la possesses the highest emission quantum yield (0.22). Moreover, the fluorescence of la in solution and solid state can be reversibly tuned by reactions with trifluoroacetic acid and triethylamine. Microarea PL studies reveal that microrods of la and these after exposure to HCl gas show typical waveguide behavior. (C) 2013 Published by Elsevier Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000315843800002 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53859]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Guanxin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Organ Solids Lab, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Photochem Lab, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jianguo,Zhang, Guanxin,Liu, Zitong,et al. New emissive organic molecule based on pyrido[3,4-g]isoquinoline framework: synthesis and fluorescence tuning as well as optical waveguide behavior[J]. TETRAHEDRON,2013,69(13):2687-2692. |
| APA | Wang, Jianguo.,Zhang, Guanxin.,Liu, Zitong.,Gu, Xingui.,Yan, Yongli.,...&Zhang, Deqing.(2013).New emissive organic molecule based on pyrido[3,4-g]isoquinoline framework: synthesis and fluorescence tuning as well as optical waveguide behavior.TETRAHEDRON,69(13),2687-2692. |
| MLA | Wang, Jianguo,et al."New emissive organic molecule based on pyrido[3,4-g]isoquinoline framework: synthesis and fluorescence tuning as well as optical waveguide behavior".TETRAHEDRON 69.13(2013):2687-2692. |
入库方式： OAI收割
来源：化学研究所
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