Experimental and Theoretical Study of Reactions between Manganese Oxide Cluster Cations and Hydrogen Sulfide
文献类型：期刊论文
| 作者 | Jia, Mei-ye1,2; He, Sheng-gui1; Ge, Mao-fa1 |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2013-12-01 |
| 卷号 | 26期号:6页码:679-686 |
| 关键词 | Cluster Oxygen-for-sulfur Exchange Reaction Mechanism Mass Spectrometry Density Functional Theory |
| ISSN号 | 1674-0068 |
| DOI | 10.1063/1674-0068/26/06/679-686 |
| 英文摘要 | Manganese oxide cluster cations (MnmOn+)-O-18 were prepared by laser ablation and reacted with hydrogen sulfide (H2S) in a fast flow reactor under thermal collision conditions. A time-of-flight mass spectrometer was used to detect the cluster distributions before and after the interactions with H-2 S. The experiments suggest that oxygen-for-sulfur (O/S) exchange reaction to release water took place in the reactor for most of the manganese oxide cluster cations: (MnmOn+)-O-18+H2S ->(MnmOn-1S+)-O-18+(H2O)-O-18. Density functional theory calculations were performed for reaction mechanisms of Mn2O2++H2S, Mn2O3++H2S, and Mn2O4++H2S. The computational results indicate these O/S exchange reactions are both thermodynamically and kinetically favorable, thus in good agreement with the experimental observations. The O/S exchange reactions identified in this gas-phase cluster study parallel similar behavior of related condensed phase reaction systems. |
| 语种 | 英语 |
| WOS记录号 | WOS:000330591600010 |
| 出版者 | CHINESE PHYSICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/53945]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He, Sheng-gui |
| 作者单位 | 1.Chinese Acad Sci, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Mei-ye,He, Sheng-gui,Ge, Mao-fa. Experimental and Theoretical Study of Reactions between Manganese Oxide Cluster Cations and Hydrogen Sulfide[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2013,26(6):679-686. |
| APA | Jia, Mei-ye,He, Sheng-gui,&Ge, Mao-fa.(2013).Experimental and Theoretical Study of Reactions between Manganese Oxide Cluster Cations and Hydrogen Sulfide.CHINESE JOURNAL OF CHEMICAL PHYSICS,26(6),679-686. |
| MLA | Jia, Mei-ye,et al."Experimental and Theoretical Study of Reactions between Manganese Oxide Cluster Cations and Hydrogen Sulfide".CHINESE JOURNAL OF CHEMICAL PHYSICS 26.6(2013):679-686. |
入库方式： OAI收割
来源：化学研究所
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