Half-Titanocene chlorides 2-(benzimidazol-2-yl)quinolin-8-olates: Synthesis, characterization and ethylene (co-)polymerization behavior
文献类型：期刊论文
| 作者 | Zhang, Wen-juan; Huang, Wei; Liang, Tong-ling; Sun, Wen-hua1
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| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2013-04-01 |
| 卷号 | 31期号:4页码:601-609 |
| 关键词 | Half-titanocene 2-(Benzimidazol-2-yl)Quinolin-8-ol Ethylene Polymerization Co-polymerization |
| ISSN号 | 0256-7679 |
| DOI | 10.1007/s10118-013-1253-4 |
| 英文摘要 | A series of half-titanocene chloride 2-(benzimidazol-2-yl)quinolin-8-olates C1-C6 were synthesized by treating the lithium salts of the ligand with CpTiCl3. All the complexes were characterized by H-1-NMR, C-13-NMR and elemental analyses, and the crystal structure of C3 and C6 was measured by X-ray. These half-titanocene complexes showed moderate catalytic activities toward ethylene polymerization (up to 1840 kg center dot mol(-1)(Ti)center dot h(-1)) when activated with MMAO, affording the high molecular weight polymers. And they also exhibited good activity for copolymerization of ethylene and alpha-olefin with low content of co-monomer. |
| 语种 | 英语 |
| WOS记录号 | WOS:000316079600007 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54009]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Wen-juan,Huang, Wei,Liang, Tong-ling,et al. Half-Titanocene chlorides 2-(benzimidazol-2-yl)quinolin-8-olates: Synthesis, characterization and ethylene (co-)polymerization behavior[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2013,31(4):601-609. |
| APA | Zhang, Wen-juan,Huang, Wei,Liang, Tong-ling,&Sun, Wen-hua.(2013).Half-Titanocene chlorides 2-(benzimidazol-2-yl)quinolin-8-olates: Synthesis, characterization and ethylene (co-)polymerization behavior.CHINESE JOURNAL OF POLYMER SCIENCE,31(4),601-609. |
| MLA | Zhang, Wen-juan,et al."Half-Titanocene chlorides 2-(benzimidazol-2-yl)quinolin-8-olates: Synthesis, characterization and ethylene (co-)polymerization behavior".CHINESE JOURNAL OF POLYMER SCIENCE 31.4(2013):601-609. |
入库方式： OAI收割
来源：化学研究所
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