A benzo[1,2-b: 4,5-b ']difuran- and thieno-[3,4-b]thiophene-based low bandgap copolymer for photovoltaic applications
文献类型：期刊论文
| 作者 | Liu, Bo1,2; Chen, Xuewen2; Zou, Yingping1,2,3; He, Yuehui1; Xiao, Lu2; Xu, Xinjun4; Li, Lidong4; Li, Yongfang5 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 4期号:3页码:470-476 |
| ISSN号 | 1759-9954 |
| DOI | 10.1039/c2py20580g |
| 英文摘要 | A new low bandgap conjugated polymer-PBDFTT-C was synthesized from thieno-[3,4-b] thiophene and benzo[1,2-b:4,5-b'] difuran units by Stille coupling reactions. The structure was verified by H-1 NMR and elemental analysis, the molecular weight was determined by gel permeation chromatography (GPC) and the thermal properties were investigated by thermogravimetric analysis (TGA). PBDFTT-C showed a low HOMO energy level of -5.27 eV. The polymer film displayed broad absorption in the wavelength region from 300 nm to 840 nm with a low bandgap of 1.48 eV. The field effect hole mobility of PBDFTT-C reached 5.4 x 10(-3) cm(2) V-1 s(-1). By using 1,8-diiodooctane (DIO) as the solvent additive, photovoltaic cells with the structure of ITO/PEDOT:PSS/PBDFTT-C:PC71BM (1 : 1.5, w/w)/Ca/Al demonstrated a power conversion efficiency of 4.4% with a short circuit current of 10.45 mA cm(-2), open circuit voltage of 0.66 V and a fill factor of 0.64, under the illumination of AM 1.5G, 100 mW cm(-2). |
| 语种 | 英语 |
| WOS记录号 | WOS:000312947100008 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54167]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zou, Yingping |
| 作者单位 | 1.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China 2.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China 3.Cent S Univ, Inst Super Microstruct & Ultrafast Proc, Changsha 410083, Hunan, Peoples R China 4.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Bo,Chen, Xuewen,Zou, Yingping,et al. A benzo[1,2-b: 4,5-b ']difuran- and thieno-[3,4-b]thiophene-based low bandgap copolymer for photovoltaic applications[J]. POLYMER CHEMISTRY,2013,4(3):470-476. |
| APA | Liu, Bo.,Chen, Xuewen.,Zou, Yingping.,He, Yuehui.,Xiao, Lu.,...&Li, Yongfang.(2013).A benzo[1,2-b: 4,5-b ']difuran- and thieno-[3,4-b]thiophene-based low bandgap copolymer for photovoltaic applications.POLYMER CHEMISTRY,4(3),470-476. |
| MLA | Liu, Bo,et al."A benzo[1,2-b: 4,5-b ']difuran- and thieno-[3,4-b]thiophene-based low bandgap copolymer for photovoltaic applications".POLYMER CHEMISTRY 4.3(2013):470-476. |
入库方式： OAI收割
来源：化学研究所
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