On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid-Vapor Interface Reactions
文献类型：期刊论文
| 作者 | Liu, Xuan-He1,2,3; Guan, Cui-Zhong1,2,3; Ding, San-Yuan4; Wang, Wei4; Yan, Hui-Juan1,2; Wang, Dong1,2; Wan, Li-Jun1,2 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2013-07-17 |
| 卷号 | 135期号:28页码:10470-10474 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja403464h |
| 英文摘要 | Surface covalent organic frameworks (SCOFs), featured by atomic thick sheet with covalently bonded organic building units, are promised to possess unique properties associated with reduced dimensionality, well-defined in-plane structure, and tunable functionality. Although a great deal of effort has been made to obtain SCOFs with different linkages and building blocks via both "top-down" exfoliation and "bottom-up" surface synthesis approaches, the obtained SCOFs generally suffer a low crystallinity, which impedes the understanding of intrinsic properties of the materials. Herein, we demonstrate a self-limiting solid-vapor interface reaction strategy to fabricate highly ordered SCOFs. The coupling reaction is tailored to take place at the solid-vapor interface by introducing one precursor via vaporization to the surface preloaded with the other precursor. Following this strategy, highly ordered honeycomb SCOFs with imine linkage are obtained. The controlled formation of SCOFs in our study shows the possibility of a rational design and synthesis of SCOFs with desired functionality. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322103000057 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54175]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ CAS, Beijing 100049, Peoples R China 4.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xuan-He,Guan, Cui-Zhong,Ding, San-Yuan,et al. On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid-Vapor Interface Reactions[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2013,135(28):10470-10474. |
| APA | Liu, Xuan-He.,Guan, Cui-Zhong.,Ding, San-Yuan.,Wang, Wei.,Yan, Hui-Juan.,...&Wan, Li-Jun.(2013).On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid-Vapor Interface Reactions.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,135(28),10470-10474. |
| MLA | Liu, Xuan-He,et al."On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid-Vapor Interface Reactions".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135.28(2013):10470-10474. |
入库方式： OAI收割
来源：化学研究所
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