Synthesis, Structure and Coordination Self-Assembly of Azacalix[4-n]pyridine[n]pyrazines (n=1-3)
文献类型：期刊论文
| 作者 | Wu, Jincheng2; Zhao, Liang1; Wang, Dexian2; Wang, Meixiang1 |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2013-05-01 |
| 卷号 | 31期号:5页码:589-597 |
| 关键词 | Calixarenes Coordination Networks Self-assembly Macrocyclic Pyrazine |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201300078 |
| 英文摘要 | We herein report the synthesis and metal-directed coordination self-assembly behaviors of three new macrocyclic azacalix[4]aromatics that comprise various numbers of pyridine and pyrazine rings bridged by N-CH3 groups. Structural characterization of 13 explored that their conformations are fluxional in solution and each adopts a 1,3-alternate configuration in crystalline solids. The macrocyclic skeletons in azacalixaromatic 13 afford a good platform to designedly arrange coordination sites in a unique way relative to conventional multidentate ligands. Solid-state structures of three coordination self-assembled silver complexes (1315) of 13 determined by X-ray crystallography suggest that the nitrogen atoms on procumbent aromatics have better coordination ability than those on perpendicular aromatics and dictate the whole coordination self-assemblies. Unique discrete and 1D chain-like structures were thus obtained. This system may afford a deeper insight into the coordination self-assembly studies of heteroatom-bridged calixaromatics, possibly extending potential application of this novel macrocyclic polydentate organic compounds in the synthesis of functional metal organic framework formation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000319349300008 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54233]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, Liang |
| 作者单位 | 1.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Jincheng,Zhao, Liang,Wang, Dexian,et al. Synthesis, Structure and Coordination Self-Assembly of Azacalix[4-n]pyridine[n]pyrazines (n=1-3)[J]. CHINESE JOURNAL OF CHEMISTRY,2013,31(5):589-597. |
| APA | Wu, Jincheng,Zhao, Liang,Wang, Dexian,&Wang, Meixiang.(2013).Synthesis, Structure and Coordination Self-Assembly of Azacalix[4-n]pyridine[n]pyrazines (n=1-3).CHINESE JOURNAL OF CHEMISTRY,31(5),589-597. |
| MLA | Wu, Jincheng,et al."Synthesis, Structure and Coordination Self-Assembly of Azacalix[4-n]pyridine[n]pyrazines (n=1-3)".CHINESE JOURNAL OF CHEMISTRY 31.5(2013):589-597. |
入库方式： OAI收割
来源：化学研究所
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