Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy
文献类型：期刊论文
| 作者 | Liu AnAn1; Huang Zhi1; Deng GangHua2; Guo Yuan3 |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2013-05-01 |
| 卷号 | 58期号:13页码:1529-1535 |
| 关键词 | Air/water Interface Sum Frequency Generation Adsorption Isotherm Benzonitrile |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-013-5763-9 |
| 英文摘要 | In this investigation, the adsorption of benzonitrile at the air/water interface was addressed using vibrational sum-frequency spectroscopy. Using ppp and ssp polarization combinations, the authors detected the symmetric stretching mode of the cyano (CN) group and calculated the orientation of benzonitrile at the interface. In addition, the adsorption isotherm was determined in terms of the hyperpolarizability element by varying the bulk benzonitrile concentration. The adsorption energy was obtained from fitting this isotherm. This work will add to our understanding of chemical processes relevant to retention, degradation, and photolysis of benzonitriles in the environment. |
| 语种 | 英语 |
| WOS记录号 | WOS:000318527200008 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54297]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo Yuan |
| 作者单位 | 1.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu AnAn,Huang Zhi,Deng GangHua,et al. Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy[J]. CHINESE SCIENCE BULLETIN,2013,58(13):1529-1535. |
| APA | Liu AnAn,Huang Zhi,Deng GangHua,&Guo Yuan.(2013).Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy.CHINESE SCIENCE BULLETIN,58(13),1529-1535. |
| MLA | Liu AnAn,et al."Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy".CHINESE SCIENCE BULLETIN 58.13(2013):1529-1535. |
入库方式： OAI收割
来源：化学研究所
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