Cu(II)-Catalyzed Allylic Silylation of Morita-Baylis-Hillman Alcohols via Dual Activation of Si-B Bond and Hydroxyl Group
文献类型：期刊论文
| 作者 | Xuan, Qing-Qing1,2; Zhong, Neng-Jun1,2; Ren, Chuan-Li1,2; Liu, Li1; Wang, Dong1; Chen, Yong-Jun1; Li, Chao-Jun3 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2013-11-01 |
| 卷号 | 78期号:21页码:11076-11081 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo4016419 |
| 英文摘要 | The reaction of Morita-Baylis-Hillman (MBH) alcohols with Me(2)PhSiBpin under the catalysis of Cu(OTf)(2)/pyridine in methanol has been developed. The direct silylation of allylic alcohols via dual activation of the Si-B bond and the hydroxyl group of the MBH alcohol provides an efficient and convenient method for the synthesis of functionalized allylsilanes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000326615300054 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54341]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Li |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.McGill Univ, Dept Chem, Montreal, PQ H3A 0B8, Canada |
| 推荐引用方式 GB/T 7714 | Xuan, Qing-Qing,Zhong, Neng-Jun,Ren, Chuan-Li,et al. Cu(II)-Catalyzed Allylic Silylation of Morita-Baylis-Hillman Alcohols via Dual Activation of Si-B Bond and Hydroxyl Group[J]. JOURNAL OF ORGANIC CHEMISTRY,2013,78(21):11076-11081. |
| APA | Xuan, Qing-Qing.,Zhong, Neng-Jun.,Ren, Chuan-Li.,Liu, Li.,Wang, Dong.,...&Li, Chao-Jun.(2013).Cu(II)-Catalyzed Allylic Silylation of Morita-Baylis-Hillman Alcohols via Dual Activation of Si-B Bond and Hydroxyl Group.JOURNAL OF ORGANIC CHEMISTRY,78(21),11076-11081. |
| MLA | Xuan, Qing-Qing,et al."Cu(II)-Catalyzed Allylic Silylation of Morita-Baylis-Hillman Alcohols via Dual Activation of Si-B Bond and Hydroxyl Group".JOURNAL OF ORGANIC CHEMISTRY 78.21(2013):11076-11081. |
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来源：化学研究所
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