中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hybrid molecular nanostructures with donor-acceptor chains

文献类型:期刊论文

作者Yang Liu1,2; Guan CuiZhong1,2; Yue Wan1,2; Wu JingYi1; Yan HuiJuan1; Zhang Xu1; Wang ZhaoHui1; Zhan XiaoWei1; Li YuLiang1; Wang Dong1
刊名SCIENCE CHINA-CHEMISTRY
出版日期2013
卷号56期号:1页码:124-130
关键词Phase Separation Donor And Acceptor Self-assembly Hybrid Molecular Nanostructure Liquid/solid Interface
ISSN号1674-7291
DOI10.1007/s11426-012-4666-y
英文摘要We have fabricated hybrid molecular chain structures formed by electron acceptor compound 1 and electron donor molecules 2 and 3 at the liquid/solid interface of graphite surface. The structural details of the mono-component and the binary assemblies are revealed by high resolution scanning tunneling microscopy (STM). Compound 1 can form two well-ordered lamellar patterns at different concentrations. In the co-adsorption structures, compounds 2 and 3 can insert into the space between molecular chains of compound 1 and form large area well-ordered nanoscale phase separated lamellar structures. The unit cell parameters for the coassemblies can be "flexibly" adjusted to make the electron donors and acceptors perfectly match along the molecular chains. Scanning tunneling spectroscopy (STS) results indicate that the electronic properties of individual molecular donors and acceptors are preserved in the binary self-assembly. These results provide molecular insight into the nanoscale phase separation of organic electron acceptors and donors on surfaces and are helpful for the fabrication of surface supramolecular structures and molecular devices.
语种英语
WOS记录号WOS:000313456500015
出版者SCIENCE PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/54399]  
专题中国科学院化学研究所
通讯作者Wang Dong
作者单位1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yang Liu,Guan CuiZhong,Yue Wan,et al. Hybrid molecular nanostructures with donor-acceptor chains[J]. SCIENCE CHINA-CHEMISTRY,2013,56(1):124-130.
APA Yang Liu.,Guan CuiZhong.,Yue Wan.,Wu JingYi.,Yan HuiJuan.,...&Wan LiJun.(2013).Hybrid molecular nanostructures with donor-acceptor chains.SCIENCE CHINA-CHEMISTRY,56(1),124-130.
MLA Yang Liu,et al."Hybrid molecular nanostructures with donor-acceptor chains".SCIENCE CHINA-CHEMISTRY 56.1(2013):124-130.

入库方式: OAI收割

来源:化学研究所

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