Synthesis and photosensitivity of azobenzene functionalized hydroxypropylcellulose
文献类型：期刊论文
| 作者 | Huang, Yizhong1,2; Kang, Hongliang2; Li, Guanghua1; Wang, Chunying1; Huang, Yong2,3; Liu, Ruigang2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2013 |
| 卷号 | 3期号:36页码:15909-15916 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c3ra43031f |
| 英文摘要 | Azobenzene functionalized hydroxypropyl cellulose derivatives (azo-HPCs) with different degrees of substitution with azobenzene moieties were synthesized and characterized. The degree of substitution with the azobenzene moieties (DSazo) can be adjusted by changing the feed ratio in the reaction mixture. The photosensitivity of the azo-HPCs in both solution and solution film was investigated. The azobenzene moieties of the azo-HPCs exhibited a reversible cis-to-trans isomerization transition upon irradiation with UV and visible light in both solution and the solid state. The reversible trans-to-cis photoisomerization led to a change of the wettability of the azo-HPC films. Surface energy estimations suggest that the tunable film wettability was attributed to the change of the dipole moment of the azobenzene moieties in the film surface. The variation of the contact angle depends on the DSazo of the azo-HPC derivatives. A higher DSazo corresponds to a larger variation of water contact angle upon UV irradiation under the same conditions. This work offers a versatile method to manipulate the surface properties of the eco-friendly cellulose derivatives. |
| 语种 | 英语 |
| WOS记录号 | WOS:000323271700053 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54447]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Guanghua |
| 作者单位 | 1.Guangxi Univ, Coll Chem & Chem Engn, Nanning 530004, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Natl Res Ctr Engn Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Yizhong,Kang, Hongliang,Li, Guanghua,et al. Synthesis and photosensitivity of azobenzene functionalized hydroxypropylcellulose[J]. RSC ADVANCES,2013,3(36):15909-15916. |
| APA | Huang, Yizhong,Kang, Hongliang,Li, Guanghua,Wang, Chunying,Huang, Yong,&Liu, Ruigang.(2013).Synthesis and photosensitivity of azobenzene functionalized hydroxypropylcellulose.RSC ADVANCES,3(36),15909-15916. |
| MLA | Huang, Yizhong,et al."Synthesis and photosensitivity of azobenzene functionalized hydroxypropylcellulose".RSC ADVANCES 3.36(2013):15909-15916. |
入库方式： OAI收割
来源：化学研究所
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